Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Strong Axiality and Ising Exchange Interaction Suppress Zero-Field Tunneling of Magnetization of an Asymmetric Dy2 Single-Molecule Magnet

YN Guo, GF Xu, W Wernsdorfer, L Ungur… - Journal of the …, 2011 - ACS Publications
The high axiality and Ising exchange interaction efficiently suppress quantum tunneling of
magnetization of an asymmetric dinuclear DyIII complex, as revealed by combined …

Magnetic interactions in molecules and highly correlated materials: physical content, analytical derivation, and rigorous extraction of magnetic Hamiltonians

JP Malrieu, R Caballol, CJ Calzado, C De Graaf… - Chemical …, 2014 - ACS Publications
Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …

An Organometallic Building Block Approach To Produce a Multidecker 4f Single-Molecule Magnet

JJ Le Roy, M Jeletic, SI Gorelsky… - Journal of the …, 2013 - ACS Publications
An organometallic building block strategy was employed to investigate the magnetic
properties of a LnIII organometallic single-ion magnet (SIM) and subsequent single …

Modulating Magnetic Dynamics of Three Dy2 Complexes through Keto–Enol Tautomerism of the o-Vanillin Picolinoylhydrazone Ligand

YN Guo, XH Chen, S Xue, J Tang - Inorganic Chemistry, 2011 - ACS Publications
Complexation of dysprosium (III) with the heterodonor chelating ligand o-vanillin
picolinoylhydrazone (H2 ovph) in the presence of different bases affords three new …

An NCN-pincer ligand dysprosium single-ion magnet showing magnetic relaxation via the second excited state

YN Guo, L Ungur, GE Granroth, AK Powell, C Wu… - Scientific Reports, 2014 - nature.com
Single-molecule magnets are compounds that exhibit magnetic bistability purely of
molecular origin. The control of anisotropy and suppression of quantum tunneling to obtain a …

Designing quantum spaces of higher dimensionality from a tetranuclear erbium-based single-molecule magnet

AP Orlova, MG Bernbeck… - Journal of the American …, 2024 - ACS Publications
The spin relaxation of an Er3+ tetranuclear single-molecule magnet,[Er (hdcCOT) I]
4,(hdcCOT= hexahydrodicyclopentacyclooctatetraenide dianion), is modeled as a near …

Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

Heterometallic Cu II/Dy III 1D chiral polymers: chirogenesis and exchange coupling of toroidal moments in trinuclear Dy 3 single molecule magnets

G Novitchi, G Pilet, L Ungur, VV Moshchalkov… - Chemical …, 2012 - pubs.rsc.org
The first example of exchange coupling between the toroidal moments in chiral
heterometallic CuII/DyIII 1D polymers built from alternating trinuclear Dy3 SMM-building …