1, 3-P, N hybrid ligands in mononuclear coordination chemistry and homogeneous catalysis

MK Rong, F Holtrop, JC Slootweg… - Coordination Chemistry …, 2019 - Elsevier
P, N-ligands are prominent hybrid ligands which provide valuable mononuclear transition
metal complexes, due to their varied bonding modes with an inherent usefulness in …

Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization

A Zucca, MI Pilo - Molecules, 2021 - mdpi.com
Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This
reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode …

Design, synthesis and evaluation of novel 1, 2, 4-triazole derivatives as promising anticancer agents

L Emami, S Sadeghian, A Mojaddami, S Khabnadideh… - BMC chemistry, 2022 - Springer
Herein, we reported the synthesis of nineteen novel 1, 2, 4-triazole derivatives including 1, 3-
diphenyl-2-(1H-1, 2, 4-triazol-1-yl) propan-1-ones (7a-e), 1-(1, 3-diphenylpropan-2-yl)-1 H-1 …

Rollover cyclometalated bipyridine platinum complexes as potent anticancer agents: impact of the ancillary ligands on the mode of action

MV Babak, M Pfaffeneder-Kmen… - Inorganic …, 2018 - ACS Publications
Platinum-based anticancer coordination compounds are widely used in the treatment of
many tumor types, where they are very effective but also cause severe side effects …

Half-Sandwich Cyclometalated RhIII Complexes Bearing Thiolate Ligands: Biomolecular Interactions and In Vitro and In Vivo Evaluations

A Nahaei, Z Mandegani, S Chamyani… - Inorganic …, 2022 - ACS Publications
A class of cyclometalated RhIII complexes [Cp* Rh (ppy)(SR)] bearing thiolate ligands, Cp*=
pentamethylcyclopentadienyl, ppy= 2-phenylpyridinate, and R= pyridyl (Spy, 2), pyrimidyl …

Cyclometalated Platinum(II) Complexes Bearing Bidentate O,O′-Di(alkyl)dithiophosphate Ligands: Photoluminescence and Cytotoxic Properties

M Fereidoonnezhad, B Kaboudin, T Mirzaee… - …, 2017 - ACS Publications
Mononuclear complexes [Pt (ppy)(S∧ S)](1a, S∧ S= O, O′-di (cyclohexyl) dithiophosphate
(ctp); 2a, S∧ S= O, O′-di (butyl) dithiophosphate (btp)) and [Pt (bzq)(S∧ S)](1b, S∧ S= ctp; …

Fluorinated cycloplatinated (II) complexes bearing bisphosphine ligands as potent anticancer agents

HR Shahsavari, J Hu, S Chamyani, Y Sakamaki… - …, 2020 - ACS Publications
A family of cationic cycloplatinated (II) complexes [Pt (dfppy)(P^ P)] Cl incorporating
bisphosphine ligands was prepared:(dfppy= 2-(2, 4-difluorophenyl) pyridine; P^ P= bis …

Luminescent cycloplatinated complexes with biologically relevant phosphine ligands: optical and cytotoxic properties

G Millán, N Giménez, R Lara, JR Berenguer… - Inorganic …, 2019 - ACS Publications
Two series of neutral luminescent pentafluorophenyl cycloplatinated (II) complexes [Pt (C^
N)(C6F5) L][C^ N= C-deprotonated 2-phenylpyridine (ppy; a), 2-(2, 4-difluorophenylpyridine …

Palladium (II) complexes based on Schiff base ligands derived from ortho-vanillin; synthesis, characterization and cytotoxic studies

Z Faghih, A Neshat, A Wojtczak, Z Faghih… - Inorganica Chimica …, 2018 - Elsevier
Methoxy-2-[(E)-Aryliminomethyl]-phenol (Aryl= Phenyl; 2, 6-dimethyl; 2, 6-diisopropylphenyl;
2, 6-dichlorophenyl), comprising L 1–L 4 ligands, and palladium complexes [Pd (L n) 2, n= 1 …

Synthesis and biological evaluation of thiolate gold (i) complexes as thioredoxin reductase (TrxR) and glutathione reductase (GR) inhibitors

M Fereidoonnezhad, HA Mirsadeghi… - New Journal of …, 2019 - pubs.rsc.org
New gold (I) thiolate complexes [(PPh2py) Au (SR)](PPh2py= 2-(diphenylphosphino)
pyridine and SR= the deprotonated form of pyridine-2-thiol (HSpy, 1a), pyrimidine-2 thiol …