Decarboxylative halogenation, or halodecarboxylation, represents one of the fundamental
key methods for the synthesis of ubiquitous organic halides. The method is based on …

Organosulfur functionalities are ubiquitous in nature, pharmaceuticals, agrochemicals,
materials and flavourants. Historically, these moieties were introduced almost exclusively …

Fluorine, often called as “a small atom with a big ego”, 1 lies in the second row and the 17th
column in the periodic table of the chemical elements. This unique position in the periodic …

A direct, catalytic hydrodecarboxylation of primary, secondary, and tertiary carboxylic acids
is reported. The catalytic system consists of a Fukuzumi acridinium photooxidant with …

Decarboxylative halogenation reactions of alkyl carboxylic acids are highly valuable
reactions for the synthesis of structurally diverse alkyl halides. However, many reported …

At last count, nearly 5000 halogenated natural products have been discovered. In
approximately half of these compounds, the carbon atom to which the halogen is bound is …

Tertiary carbon radicals have notable utility for uniting complex carbon fragments with
concomitant formation of new quaternary carbons. This article explores the scope …

A suitable protocol for the photocatalytic decarboxylation of carboxylic acids was developed
with metal-free ceramic boron carbon nitrides (BCN). With visible light irradiation, BCN …

Carboxylic acids are among the most used feedstock chemicals due to their great structural
diversity and easy handling. The use of carboxylic acids and their derivatives in …

AGd (kcal/mol) ke* q (M'] s"=) la 88 92 82-30.5 7.9 X 109 lb 98 84 84-31.0 8.3 X 109 lc 84 87
75-33.0 8.9 X 109 “[substrate]= 0.5-3.1 X 10" 3 M,[sensitizer]= 0.8-1.7 x" 3 M in/-PrOH-H20 …