Donor and donor–donor carbenes are two important kinds of carbenes, which have
experienced tremendous growth in the past two decades. This review provides a …

C–H functionalization has become widely recognized as an exciting new strategy for the
synthesis of complex molecular targets. Instead of relying on functional groups as the …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

Donor/donor carbenes are relatively new in the field of carbene chemistry; although
applications in C− H and X− H insertion reactions are few in number, they demonstrate …

Stereoselective cyclopropanation reaction of alkenes is usually achieved by metal
complexes via singlet‐metal‐carbene intermediates. However, previous transition‐metal …

Herein, we report an achiral dirhodium complex and chiral phosphoric acid cooperatively
catalyzed asymmetric three-component reaction of enynal with alcohol and imine, affording …

Described herein is an enantioselective dirhodium (II)-catalyzed cycloisomerization of
diynes achieved by the strategy of desymmetrization, which not only represents a new …

Alkanes are an abundant and valuable resource for transformation into value-added fine
chemicals. However, selective functionalization of specific C (sp 3)–H bonds in alkanes for …

Dirhodiums, which feature lantern-or paddlewheel-like structures, have emerged as a class
of useful catalysts in organic synthesis. Among the transformations catalyzed by dirhodiums …

The catalytic asymmetric cyclopropanation reaction of alkenes with diazo compounds is a
direct and powerful method to construct chiral cyclopropanes that are essential to drug …