Photoreforming (PR) is a process that splits water into hydrogen coupled with oxidation of
solid waste into value‐added products, which provides a way to mitigate resource depletion …

The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

C–N axially chiral skeletons are ubiquitous in bioactive natural products, pharmaceuticals,
and chiral ligands. However, their atroposelective synthesis remains a formidable challenge …

Due to the dichotomy between reactivity and stereoselectivity, the synthesis of axially chiral
biaryls via enantioselective C–H arylation remains a daunting challenge. This full account …

Planar chiral metallocenes have found application in the fields of asymmetric catalysis,
medicinal chemistry and materials science. Asymmetric C–H functionalisation provides an …

The Catellani reaction, ie, the Pd/norbornene (NBE) catalysis, has been evolved into a
versatile approach to multisubstituted arenes via the ortho-functionalization/ipso-termination …

The preparation of ferrocenes with both axial and planar chiralities poses a considerable
challenge. Herein, we report a strategy for the construction of both axial and planar …

Comprehensive Summary Herein, we report an asymmetric two‐component alkenyl
Catellani reaction for the construction of C—N axial chirality through a palladium/chiral …

The asymmetric catalytic addition of linear Grignard reagents to ketones has been a long‐
standing challenge in organic synthesis. Herein, a novel family of PNP ligands (W‐Phos) …

The present work demonstrates a palladium-catalyzed kinetic resolution/ring-opening
reaction of 8 H-indeno [1, 2-c] thiophen-8-ols. The reaction proceeds in a highly …