Non-heme iron catalysts for epoxidation and aziridination reactions of challenging terminal alkenes: towards sustainability

A Fingerhut, OV Serdyuk, SB Tsogoeva - Green Chemistry, 2015 - pubs.rsc.org
Through catalytic epoxidation and aziridination of olefins versatile synthetic intermediates
and subunits of biologically active compounds and pharmaceuticals–epoxides and …

Historical landmarks of the application of molecular transition metal catalysts for olefin epoxidation

S Huber, M Cokoja, FE Kuehn - Journal of organometallic chemistry, 2014 - Elsevier
Various polymers, fine chemicals, pharmaceuticals, food additives and flavor & fragrance
compounds are based on epoxide intermediates. This historical perspective covers the …

Aerobic oxysulfonylation of alkenes leading to secondary and tertiary β-hydroxysulfones.

Q Lu, J Zhang, F Wei, Y Qi, H Wang… - Angewandte …, 2013 - search.ebscohost.com
Dioxygen is not only a green oxidant but also an ideal oxygen source for the
functionalization of organic molecules.[1] Dioxygen activation has been of long-standing …

Monodisperse magnetite nanoparticles with nearly ideal saturation magnetization

SJ Kemp, RM Ferguson, AP Khandhar, KM Krishnan - RSC advances, 2016 - pubs.rsc.org
We present a scalable thermolysis and high temperature oxidation procedure for
synthesizing monodisperse magnetite nanoparticles with saturation magnetization of up to …

Catalyst Complexity in a Highly Active and Selective Wacker-Type Markovnikov Oxidation of Olefins with a Bioinspired Iron Complex

J Trouvé, K Youssef, S Kasemthaveechok… - ACS …, 2023 - ACS Publications
Palladium-catalyzed Wacker-type reactions occupy a central place in organic synthesis with
important implications in industry. Pursuing more benign protocols by replacing palladium …

A direct approach to β-keto sulfones via AgNO3/K2S2O8 catalyzed aerobic oxysulfonylation of alkenes in aqueous medium

AK Singh, R Chawla, LDS Yadav - Tetrahedron Letters, 2014 - Elsevier
Abstract An efficient, AgNO 3/K 2 S 2 O 8 catalyzed one-pot radical route to β-keto sulfones
from alkenes is reported. The protocol involves oxysulfonylation of alkenes with air (O 2) and …

Continuous flow epoxidation of alkenes using a homogeneous manganese catalyst with peracetic acid

AA Ryan, SD Dempsey, M Smyth, K Fahey… - … Process Research & …, 2023 - ACS Publications
Epoxidation of alkenes is a valuable transformation in the synthesis of fine chemicals.
Described herein are the design and development of a continuous flow process for carrying …

K2S2O8‐Mediated Aerobic Oxysulfonylation of Olefins into β‐Keto Sulfones in Aqueous Media

R Chawla, AK Singh, LDS Yadav - European Journal of …, 2014 - Wiley Online Library
Abstract β‐Keto sulfones were obtained in good to excellent yields (73–94%) directly from
unactivated olefins by employing inexpensive sodium arenesulfinate salts as sulfonylating …

Covalently functionalized graphene oxide metal complexes: Versatile nanocatalysts for organic transformations

A Sharma, S Sharma, S Yadav, B Arora, S Dutta… - Materials Science and …, 2024 - Elsevier
Catalysis is one of the fundamental pillars of green chemistry which can assist in meeting
those challenges through the advancement in design and development of greener synthetic …

Towards sustainable polymer chemistry with homogeneous metal-based catalysts

K Schröder, K Matyjaszewski, KJT Noonan… - Green …, 2014 - pubs.rsc.org
In the last two decades, numerous catalytic methods have become woven into the fabric of
green and sustainable chemistry. In order to qualitatively evaluate and construct a tangible …