Criegee intermediates and their impacts on the troposphere
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
The effect of ozone addition on combustion: Kinetics and dynamics
Ozone addition is a promising method to enhance and control combustion and ignition
processes. It can be produced efficiently at atmospheric or elevated pressure conditions and …
processes. It can be produced efficiently at atmospheric or elevated pressure conditions and …
Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
Atmospheric kinetics: bimolecular reactions of carbonyl oxide by a triple-level strategy
Criegee intermediates in the atmosphere serve as oxidizing agents to initiate aerosol
formation, which are particularly important for atmospheric modeling, and understanding …
formation, which are particularly important for atmospheric modeling, and understanding …
Criegee intermediates: What direct production and detection can teach us about reactions of carbonyl oxides
CA Taatjes - Annual Review of Physical Chemistry, 2017 - annualreviews.org
The carbonyl oxide intermediates in the ozonolysis of alkenes, often known as Criegee
intermediates, are potentially important reactants in Earth's atmosphere. For decades …
intermediates, are potentially important reactants in Earth's atmosphere. For decades …
Criegee intermediate–alcohol reactions, a potential source of functionalized hydroperoxides in the atmosphere
MR McGillen, BFE Curchod… - ACS Earth and Space …, 2017 - ACS Publications
Ozonolysis, the mechanism by which alkenes are oxidized by ozone in the atmosphere,
produces a diverse family of oxidants known as Criegee intermediates (CIs). Using a …
produces a diverse family of oxidants known as Criegee intermediates (CIs). Using a …
The reaction of Criegee intermediates with acids and enols
L Vereecken - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
The reaction of CH2OO, the smallest carbonyl oxide (Criegee intermediate, CI), with several
acids was investigated using the CCSD (T)/aug-cc-pVTZ//M06-2X/aug-cc-pVTZ quantum …
acids was investigated using the CCSD (T)/aug-cc-pVTZ//M06-2X/aug-cc-pVTZ quantum …
Direct gas-phase formation of formic acid through reaction of Criegee intermediates with formaldehyde
Ozonolysis of isoprene is considered to be an important source of formic acid (HCOOH), but
its underlying reaction mechanisms related to HCOOH formation are poorly understood …
its underlying reaction mechanisms related to HCOOH formation are poorly understood …
Unimolecular reaction of acetone oxide and its reaction with water in the atmosphere
Criegee intermediates (ie, carbonyl oxides with two radical sites) are known to be important
atmospheric reagents; however, our knowledge of their reaction kinetics is still limited …
atmospheric reagents; however, our knowledge of their reaction kinetics is still limited …
Kinetics of the Simplest Criegee Intermediate Reaction with Water Vapor: Revisit and Isotope Effect
YJ Wu, K Takahashi, JJM Lin - The Journal of Physical Chemistry …, 2023 - ACS Publications
The kinetics of the simplest Criegee intermediate (CH2OO) reaction with water vapor was
revisited. By improving the signal-to-noise ratio and the precision of water concentration, we …
revisited. By improving the signal-to-noise ratio and the precision of water concentration, we …