Pure hydrocarbon cycles in TMC-1: Discovery of ethynyl cyclopropenylidene, cyclopentadiene, and indene

J Cernicharo, M Agúndez, C Cabezas… - Astronomy & …, 2021 - aanda.org
We report the detection for the first time in space of three new pure hydrocarbon cycles in
TMC-1: cC 3 HCCH (ethynyl cyclopropenylidene), cC 5 H 6 (cyclopentadiene), and cC 9 H 8 …

Discovery of the pure polycyclic aromatic hydrocarbon indene (c-C9H8) with GOTHAM observations of TMC-1

AM Burkhardt, KLK Lee, PB Changala… - The Astrophysical …, 2021 - iopscience.iop.org
Polycyclic aromatic hydrocarbons (PAHs) have long been invoked in the study of interstellar
and protostellar sources, but the unambiguous identification of any individual PAH has …

Discovery of benzyne, o-C6H4, in TMC-1 with the QUIJOTE line survey

J Cernicharo, M Agúndez, RI Kaiser… - Astronomy & …, 2021 - aanda.org
We report the detection, for the first time in space, of a new non-functionalised hydrocarbon
cycle in the direction of TMC-1: oC 6 H 4 (ortho-benzyne). We derive a column density for …

Discovery of interstellar 2-cyanoindene (2-C9H7CN) in GOTHAM observations of TMC-1

ML Sita, PB Changala, C Xue… - The Astrophysical …, 2022 - iopscience.iop.org
We present laboratory rotational spectroscopy of five isomers of cyanoindene (2-, 4-, 5-, 6-,
and 7-cyanoindene) using a cavity Fourier transform microwave spectrometer operating …

The 2023 release of Cloudy

M Chatzikos, S Bianchi, F Camilloni… - arXiv preprint arXiv …, 2023 - arxiv.org
We describe the 2023 release of the spectral synthesis code Cloudy. Since the previous
major release, migrations of our online services motivated us to adopt git as our version …

Efficient stabilization of cyanonaphthalene by fast radiative cooling and implications for the resilience of small PAHs in interstellar clouds

MH Stockett, JN Bull, H Cederquist, S Indrajith… - Nature …, 2023 - nature.com
After decades of searching, astronomers have recently identified specific Polycyclic Aromatic
Hydrocarbons (PAHs) in space. Remarkably, the observed abundance of cyanonaphthalene …

An aromatic universe–A physical chemistry perspective

RI Kaiser, N Hansen - The Journal of Physical Chemistry A, 2021 - ACS Publications
This Perspective presents recent advances in our knowledge of the fundamental elementary
mechanisms involved in the low-and high-temperature molecular mass growth processes to …

Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion

P Hemberger, A Bodi, T Bierkandt, M Köhler… - Energy & …, 2021 - ACS Publications
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …

Continuous pyrolysis microreactors: Hot sources with little cooling? New insights utilizing cation velocity map imaging and threshold photoelectron spectroscopy

P Hemberger, X Wu, Z Pan, A Bodi - The Journal of Physical …, 2022 - ACS Publications
Resistively heated silicon carbide microreactors are widely applied as continuous sources to
selectively prepare elusive and reactive intermediates with astrochemical, catalytic, or …

Noncovalent Interactions Steer the Formation of Polycyclic Aromatic Hydrocarbons

DB Rap, JGM Schrauwen, B Redlich… - Journal of the …, 2024 - ACS Publications
Aromatic molecules play an important role in the chemistry of astronomical environments
such as the cold interstellar medium (ISM) and (exo) planetary atmospheres. The observed …