Conspectus Natural product research originates from a desire to explore, understand, and
perturb biological function with atomic precision. To reach these goals at all, let alone …

Due to the high reactivity of cyclopropanes, different methods have been developed for their
stereo‐and regio‐controlled ring‐opening reactions to achieve a variety of synthetically …

β2-Amino carbonyls, an α-substituted β-amino scaffold, hold a prominent place in the
development of new pharmaceuticals and peptidomimetics. Herein, we report a highly …

Neuroactive metabolites from the bark of Galbulimima belgraveana occur in variable
distributions among trees and are not easily accessible through chemical synthesis because …

Herein, we document the design and development of a novel (3+ 2) cycloaddition reaction
aided by the activity of an organic photocatalyst and visible light. The process is extremely …

Introducing alkyl groups, particularly through innovative C (sp2)–C (sp3) bond-forming
methods utilizing abundant feedstocks, holds promise for expanding chemical space …

An efficient metal-free photocatalytic method for the alkylation of alkenes using accessible
aliphatic alcohols as redox auxiliaries is presented. C-centered radicals can be generated …

The merging of transition metal catalysis with electrochemistry has become a powerful tool
for organic synthesis because catalysts can govern the reactivity and selectivity. However …

The direct use of alcohols as coupling partners via homolytic C–OH bond cleavage remains
a formidable challenge but holds great opportunities to achieve useful transformations. In …

C (sp3) hybridized fragments have been widely explored for the formation of crucial Ni-alkyl
intermediates in the field of nickel-catalyzed C (sp2)–C (sp3) coupling reactions. Traditional …