Using microemulsions: formulation based on knowledge of their mesostructure

M Gradzielski, M Duvail, PM de Molina… - Chemical …, 2021 - ACS Publications
Microemulsions, as thermodynamically stable mixtures of oil, water, and surfactant, are
known and have been studied for more than 70 years. However, even today there are still …

Hydrotropes

W Kunz, K Holmberg, T Zemb - Current Opinion in Colloid & Interface …, 2016 - Elsevier
The concepts “hydrotrope” and “hydrotropy” are reviewed with a strong focus on the
literature from recent years. The action and physical–chemical behavior of hydrotropes are …

How to explain microemulsions formed by solvent mixtures without conventional surfactants

TN Zemb, M Klossek, T Lopian… - Proceedings of the …, 2016 - National Acad Sciences
Ternary solutions containing one hydrotrope (such as ethanol) and two immiscible fluids,
both being soluble in the hydrotrope at any proportion, show unexpected solubilization …

Recycling metals by controlled transfer of ionic species between complex fluids: en route to “ienaics”

T Zemb, C Bauer, P Bauduin, L Belloni… - Colloid and Polymer …, 2015 - Springer
Recycling chemistry of metals and oxides relies on three steps: dissolution, separation and
material reformation. We review in this work the colloidal approach of the transfer of ions …

Theory of gas solubility and hydrophobic interaction in aqueous electrolyte solutions

R Okamoto, K Koga - The Journal of Physical Chemistry B, 2021 - ACS Publications
Ion-specific effects on the solubility of nonpolar solutes and on the solute–solute
hydrophobic interaction in aqueous electrolyte solutions are studied on the basis of a …

Surface tension of electrolyte interfaces: Ionic specificity within a field-theory approach

T Markovich, D Andelman, R Podgornik - The Journal of Chemical …, 2015 - pubs.aip.org
We study the surface tension of ionic solutions at air/water and oil/water interfaces by using
field-theoretical methods and including a finite proximal surface-region with ionic-specific …

Casimir amplitudes and capillary condensation of near-critical fluids between parallel plates: Renormalized local functional theory

R Okamoto, A Onuki - The Journal of Chemical Physics, 2012 - pubs.aip.org
We investigate the critical behavior of a near-critical fluid confined between two parallel
plates in contact with a reservoir by calculating the order parameter profile and the Casimir …

Theory of electrolytes including steric, attractive, and hydration interactions

R Okamoto, K Koga, A Onuki - The Journal of Chemical Physics, 2020 - pubs.aip.org
We present a continuum theory of electrolytes composed of a waterlike solvent and
univalent ions. First, we start with a density functional F for the coarse-grained solvent …

Surface tension of electrolyte solutions: A self-consistent theory

T Markovich, D Andelman, R Podgornik - Europhysics Letters, 2014 - iopscience.iop.org
We study the surface tension of electrolyte solutions at the air/water and oil/water interfaces.
Employing field-theoretical methods and considering short-range interactions of anions with …

Catanionic surfactant systems—thermodynamic and structural conditions revisited

L Chiappisi, H Yalcinkaya, VK Gopalakrishnan… - Colloid and Polymer …, 2015 - Springer
In this work, we review shortly the current state of knowledge about catanionic surfactant
systems with a focus on the detailed understanding based on the molecular buildup of such …