The role of polymer mechanochemistry in responsive materials and additive manufacturing

MA Ghanem, A Basu, R Behrou, N Boechler… - Nature Reviews …, 2021 - nature.com
The use of mechanical forces to chemically transform polymers dates back decades. In
recent years, the use of mechanochemistry to direct constructive transformations in polymers …

Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making

EM Lloyd, JR Vakil, Y Yao, NR Sottos… - Journal of the American …, 2023 - ACS Publications
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …

The rise and promise of molecular nanotopology

QH Guo, Y Jiao, Y Feng, JF Stoddart - CCS Chemistry, 2021 - chinesechemsoc.org
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …

The propensity for covalent organic frameworks to template polymer entanglement

SE Neumann, J Kwon, C Gropp, L Ma, R Giovine, T Ma… - Science, 2024 - science.org
The introduction of molecularly woven three-dimensional (3D) covalent organic framework
(COF) crystals into polymers of varying types invokes different forms of contact between filler …

Force-induced near-infrared chromism of mechanophore-linked polymers

Q Qi, G Sekhon, R Chandradat… - Journal of the …, 2021 - ACS Publications
A near-infrared (NIR) mechanophore was developed and incorporated into a poly (methyl
acrylate) chain to showcase the first force-induced NIR chromism in polymeric materials …

Doubly threaded slide-ring polycatenane networks

LF Hart, WR Lenart, JE Hertzog, J Oh… - Journal of the …, 2023 - ACS Publications
Crosslinking in polymer networks leads to intrinsic structural inhomogeneities that result in
brittle materials. Replacing fixed covalent crosslinks with mobile ones in mechanically …

Polymer mechanochemistry and the emergence of the mechanophore concept

G De Bo - Macromolecules, 2020 - ACS Publications
One hundred years ago, Hermann Staudinger proposed the macromolecular hypothesis to
explain how small molecules could covalently link together to form a larger one: polymer …

Distinctive features and challenges in catenane chemistry

HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …

Mechanochemical Release of Non‐Covalently Bound Guests from a Polymer‐Decorated Supramolecular Cage

R Küng, T Pausch, D Rasch, R Göstl… - Angewandte Chemie …, 2021 - Wiley Online Library
Supramolecular coordination cages show a wide range of useful properties including, but
not limited to, complex molecular machine‐like operations, confined space catalysis, and …

2D covalent organic framework via catenation

T Prakasam, SK Sharma, F Ravaux, F Benyettou… - Chem, 2024 - cell.com
Molecular-level structural modification is a well-established approach to impart advanced
functionality to materials that continues to be the focus of research and development in both …