Synthetic amorphous calcium phosphates (ACPs): Preparation, structure, properties, and biomedical applications

SV Dorozhkin - Biomaterials Science, 2021 - pubs.rsc.org
Amorphous calcium phosphates (ACPs) represent a metastable amorphous state of other
calcium orthophosphates (abbreviated as CaPO4) possessing variable compositional but …

[HTML][HTML] Structure and formation of amorphous calcium phosphate and its role as surface layer of nanocrystalline apatite: Implications for bone mineralization

M Edén - Materialia, 2021 - Elsevier
We provide a critical review of the chemical composition and structure of synthetic and
biogenic (bone/dentin mineral) nanocrystalline hydroxy-carbonate apatite (HCA). Such …

High Mechanical Strength Alloy‐like Minerals Prepared by Inorganic Ionic Co‐cross‐linking

Z Ma, K Kong, Y Yin, Z Guo, X Ma, Q Lin… - Advanced …, 2024 - Wiley Online Library
Alloys often combine different metals to generate superior mechanical properties. However,
it is challenging to prepare high mechanical strength minerals with similar strategies. Using …

Counterintuitive Crystallization: Rate Effects in Calcium Phosphate Nucleation at Near-Physiological pH

DP McDonogh, P Kirupananthan… - Crystal Growth & …, 2023 - ACS Publications
Calcium phosphates are widely present in geological and industrial settings and make up
the majority of our bone's inorganic content; however, their formation from solution is not fully …

The carbonate and sodium environments in precipitated and biomimetic calcium hydroxy-carbonate apatite contrasted with bone mineral: Structural insights from solid …

OF Yasar, WC Liao, R Mathew, Y Yu… - The Journal of …, 2021 - ACS Publications
Bone mineral consists of calcium hydroxy-carbonate apatite (HCA) that incorporates other
minor cation substituents, primarily Na+ (0.5–0.8 wt%). We examine the carbonate species …

[HTML][HTML] Probing oxide-based glass structures by solid-state NMR: Opportunities and limitations

M Edén - Journal of Magnetic Resonance Open, 2023 - Elsevier
This Primer critically reviews the possibilities and limitations of probing the short-range
structure of an oxide-based glass by routine magic-angle spinning (MAS) or triple-quantum …

Amorphous calcium phosphate and amorphous calcium phosphate carboxylate: synthesis and characterization

A Indurkar, R Choudhary, K Rubenis, M Nimbalkar… - ACS …, 2023 - ACS Publications
Amorphous calcium phosphate (ACP) is the first solid phase precipitated from a
supersaturated calcium phosphate solution. Naturally, ACP is formed during the initial …

Redefined ion association constants have consequences for calcium phosphate nucleation and biomineralization

DP McDonogh, JD Gale, P Raiteri… - Nature Communications, 2024 - nature.com
Calcium orthophosphates (CaPs), as hydroxyapatite (HAP) in bones and teeth are the most
important biomineral for humankind. While clusters in CaP nucleation have long been …

Pyrophosphate-stabilised amorphous calcium carbonate for bone substitution: toward a doping-dependent cluster-based model

M Merle, J Soulié, C Sassoye, P Roblin, C Rey… - …, 2022 - pubs.rsc.org
Calcium carbonates and in particular amorphous calcium carbonate (ACC) are of great
interest for bone substitution, due to their excellent biocompatibility and ability to release …

Tailoring the structure and self-activated photoluminescence of carbonated amorphous calcium phosphate nanoparticles for bioimaging applications

TR Machado, CE Zanardo, RRC Vilela… - Journal of Materials …, 2024 - pubs.rsc.org
Self-activated luminescent calcium phosphate (CaP) nanoparticles, including hydroxyapatite
(HA) and amorphous calcium phosphate (ACP), are promising for bioimaging and …