The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

The first example of the reduction of a nitro compound with HBPin catalyzed by tetra
(diisopropylamido) rare-earth metal–lithium bimetallic complexes LiRE (N i Pr2) 4 …

Hydroboration of isocyanates with HBPin was demonstrated using both catalytic and catalyst-
free approaches. In arene solvents, the reactions employed the commercially available and …

In this work, the molecular aluminium dihydride complex bearing an N, N'‐chelated
conjugated bis‐guanidinate (CBG) ligand is used as a catalyst for reducing a wide range of …

We found that bis (neopentylglycolato) diboron (B2nep2) served as a bidentate ligand and a
one-electron reducing agent for early transition metal chlorides to afford MCl4 (B2nep2) …

Nitroaromatic compounds, as hazardous industrial pollutants, have long been extensively
studied for their conversion into high-value aromatic amines. However, most of these …

Hydrometallation reactions are a powerful tool in the synthesis of saturated and unsaturated
organometallic compounds, which are commonly used as synthons in organic chemistry and …