Dynamic covalent polymer networks: a molecular platform for designing functions beyond chemical recycling and self-healing

N Zheng, Y Xu, Q Zhao, T Xie - Chemical Reviews, 2021 - ACS Publications
Dynamic covalent polymer networks (DCPN) have historically attracted attention for their
unique roles in chemical recycling and self-healing, which are both relevant for sustainable …

Advances in sustainable thermosetting resins: From renewable feedstock to high performance and recyclability

J Liu, S Wang, Y Peng, J Zhu, W Zhao, X Liu - Progress in polymer science, 2021 - Elsevier
In polymer science and industry, the important role of thermosetting resin is well-recognized.
However, most thermosets suffer from the overdependence on petroleum resource and in …

Recyclable, self-strengthening starch-based epoxy vitrimer facilitated by exchangeable disulfide bonds

N Tratnik, NR Tanguy, N Yan - Chemical Engineering Journal, 2023 - Elsevier
Epoxy vitrimers have emerged as a new class of self-healing, recyclable, and reprocessable
materials, offering new opportunities to traditional epoxy thermosets by improving life-span …

Closed-loop chemical recycling of thermosetting polymers and their applications: a review

Y Liu, Z Yu, B Wang, P Li, J Zhu, S Ma - Green Chemistry, 2022 - pubs.rsc.org
Conventional thermosets are infusible and insoluble covalently cross-linked polymers that
are difficult to recycle and reuse when discarded. Recent years have witnessed the …

Biobased covalent adaptable networks: towards better sustainability of thermosets

XL Zhao, PX Tian, YD Li, JB Zeng - Green Chemistry, 2022 - pubs.rsc.org
Thermosets have many advantages such as excellent mechanical properties, dimensional
stability, and chemical and environmental resistance, but suffer from unsustainability …

Recent development of repairable, malleable and recyclable thermosetting polymers through dynamic transesterification

T Liu, B Zhao, J Zhang - Polymer, 2020 - Elsevier
A fully polymerized (cured) thermoset is no longer capable of flow like a thermoplastic to be
recycled and reprocessed into a new object. Developing repairable, malleable and …

Internal catalysis for dynamic covalent chemistry applications and polymer science

F Van Lijsebetten, JO Holloway, JM Winne… - Chemical Society …, 2020 - pubs.rsc.org
Strong covalent chemical bonds that can also be reversed, cleaved or exchanged are the
subject of so-called dynamic covalent chemistry (DCC). Applications range from classical …

[HTML][HTML] Recyclable inherently flame-retardant thermosets: Chemistry, properties and applications

WW Klingler, A Bifulco, C Polisi, Z Huang… - Composites Part B …, 2023 - Elsevier
Thermosets are polymeric materials that contain permanent networks and thus are difficult to
recycle. They are not reprocessable once cured and often do not degrade under mild …

High-performance epoxy vitrimer with superior self-healing, shape-memory, flame retardancy, and antibacterial properties based on multifunctional curing agent

J Peng, S Xie, T Liu, D Wang, R Ou, C Guo… - Composites Part B …, 2022 - Elsevier
The lack of functionalities such as degradability, antibacterial, and flame retardancy is the
key to limit the further wide application of conventional epoxy thermosets. In this work, a …

[HTML][HTML] Lignin-based benzoxazines: A tunable key-precursor for the design of hydrophobic coatings, fire resistant materials and catalyst-free vitrimers

A Adjaoud, L Puchot, CE Federico, R Das… - Chemical Engineering …, 2023 - Elsevier
The meaningful concept of circular economy has prompted the scientific community to re-
think the design of materials. In this work, lignin-based benzoxazines (LBZs) thermosets with …