Design Concepts for Solution and Solid‐State Emitters–A Modern Viewpoint on Classical and Non‐Classical Approaches

A Huber, J Dubbert, TD Scherz… - Chemistry–A European …, 2023 - Wiley Online Library
For a long time, luminescence phenomena were strictly distinguished between the emission
of isolated molecules in dilute solutions or close‐packed structures such as in powders or …

Small is beautiful: electronic origin and synthetic evolution of single-benzene fluorophores

H Kim, Y Kim, D Lee - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Single-benzene fluorophores (SBFs) are small molecules that produce visible
light by using only one benzene ring as the sole aromatic core. This Account centers around …

Relief of excited-state antiaromaticity enables the smallest red emitter

H Kim, W Park, Y Kim, M Filatov, CH Choi… - Nature …, 2021 - nature.com
It is commonly accepted that a large π-conjugated system is necessary to realize low-energy
electronic transitions. Contrary to this prevailing notion, we present a new class of light …

An arch-bridge-type fluorophore for bridging the gap between aggregation-caused quenching (ACQ) and aggregation-induced emission (AIE)

M Huang, R Yu, K Xu, S Ye, S Kuang, X Zhu… - Chemical science, 2016 - pubs.rsc.org
Solution and solid dual photoluminescence (PL) molecules fill the substantial gap between
ACQ and AIE molecules to explore the mechanism of molecular luminescence in greater …

Single‐Benzene Dual‐Emitters Harness Excited‐State Antiaromaticity for White Light Generation and Fluorescence Imaging

Y Kim, H Kim, JB Son, M Filatov… - Angewandte Chemie …, 2023 - Wiley Online Library
Molecular emitters simultaneously generating light at different wavelengths have wide
applications. With a small molecule, however, it is challenging to realize two independent …

Molecular design for organic luminogens with efficient emission in solution and solid-state

L Zou, S Guo, H Lv, F Chen, L Wei, Y Gong, Y Liu… - Dyes and …, 2022 - Elsevier
Abstract Design and synthesis of organic luminogens with efficient emission in both solution
and solid-state (namely, dual-state emission: DSE) still face enormous challenges, a …

Red-emissive organic crystals of a single-benzene molecule: elastically bendable and flexible optical waveguide

B Liu, Q Di, W Liu, C Wang, Y Wang… - The journal of physical …, 2019 - ACS Publications
Organic crystals are easily cracked into pieces or powders under applied stress because of
their intrinsic brittle nature. This undesired mechanical property directly limits their …

Extending the Stokes Shifts of Donor–Acceptor Fluorophores by Regulating the Donor Configuration for In Vivo Three-Photon Fluorescence Imaging

S Li, M He, X Jin, W Geng, C Li, X Li, Z Zhang… - Chemistry of …, 2022 - ACS Publications
Simple donor–acceptor (D–A) molecules with large Stokes-shifted and bright near-infrared
(NIR) emissions are extremely attractive for the high-resolution three-photon fluorescence …

Efficient red‐emissive organic crystals with amplified spontaneous emissions based on a single benzene framework

B Tang, C Wang, Y Wang, H Zhang - Angewandte Chemie, 2017 - Wiley Online Library
Red‐emissive fluorophores generally consist of large π‐extended systems and thus
encounter the problem of serious fluorescence quenching in the solid state. A series of …

Side-chain engineering of organic crystals for lasing media with tunable flexibility

B Tang, S Tang, C Qu, K Ye, Z Zhang… - CCS Chemistry, 2023 - chinesechemsoc.org
Abundant high-performance organic crystals have been reported in the past decades;
however, applications of crystalline materials are seriously restricted by their notorious …