Corannulene: A curved polyarene building block for the construction of functional materials

MC Stuparu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus This Account describes a body of research in the design and synthesis of
molecular materials prepared from corannulene. Corannulene (C20H10) is a molecular …

Synthesis of corannulene-based nanographenes

EM Muzammil, D Halilovic, MC Stuparu - Communications Chemistry, 2019 - nature.com
Abstract Corannulene (C20H10) is a polycyclic hydrocarbon in which five six-membered
rings surround a central five-membered ring to construct a bowl-like aromatic structure. Here …

Corannulene-based nanographene containing helical motifs

Q Xu, C Wang, J He, X Li, Y Wang, X Chen… - Organic Chemistry …, 2021 - pubs.rsc.org
The synthesis and structural analyses of corannulene-PAH hybrids 1 with a [4] helicene
subunit and 2 with a [7] helicene subunit have been reported. The structures of 1 and 2 were …

Mechanochemical Synthesis of Corannulene Flanked N‐heterocyclic Carbene (NHC) Precursors and Preparation of Their Metal Complexes

G Hum, EM Muzammil, Y Li, F García… - … –A European Journal, 2024 - Wiley Online Library
The synthesis of new compounds is an important pillar for the advancement of the field of
chemistry and adjacent fields. In this regard, over the last decades huge efforts have been …

Electron-poor bowl-shaped polycyclic aromatic dicarboximides: Synthesis, crystal structures, and optical and redox properties

K Shoyama, D Schmidt, M Mahl, F Würthner - Organic letters, 2017 - ACS Publications
Two new bowl-shaped polycyclic aromatic hydrocarbons, based on corannulene and
naphthalene dicarboximide, are synthesized by an improved Suzuki–Miyaura cross …

Synthesis and Properties of Bis-corannulenes

D Halilovic, V Rajeshkumar, MC Stuparu - Organic Letters, 2021 - ACS Publications
Corannulenecarbaldehyde and corannulenylmethyl triphenylphosphonium bromide are
combined through the Wittig olefination reaction to furnish dicorannulenylethene with 70 …

A Distorted Hybrid Corannulene–Dibenzobistetracene

Q Xu, C Wang, D Zheng, J He, Y Wang… - The Journal of …, 2021 - ACS Publications
We have designed and synthesized a new type of distorted nanographene by Diels–Alder
and Scholl reactions that contains one dibenzobistetracene (DBT, 1) core and two end …

Photochemical synthesis and electronic properties of extended corannulenes with variable fluorination pattern

D Halilovic, M Budanović, ZR Wong… - The Journal of …, 2018 - ACS Publications
The first family of extended and fluorinated corannulenes is prepared through a highly
efficient and modular synthetic strategy. In this strategy, corannulene aldehyde could be …

Cycl [2, 2, 4] azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring

L Ruan, W Luo, H Zhang, P Liu, Y Shi, P An - Chemical Science, 2024 - pubs.rsc.org
The development of non-alternant nanographenes has attracted considerable attention due
to their unique photophysical properties. Herein, we reported a novel aza-doped, non …

Differentiating π interactions by constructing concave/convex surfaces using a bucky bowl molecule, corannulene in liquid chromatography

E Kanao, T Kubo, T Naito, T Matsumoto… - Analytical …, 2018 - ACS Publications
Convex–concave π conjugated surfaces in hemispherical bucky bowl such as corannulene
(Crn) have shown increasing utility in constructing self-assembled new functional materials …