Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …

This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

We have recently reported on several Fe catalysts for N2-to-NH3 conversion that operate at
low temperature (− 78° C) and atmospheric pressure while relying on a very strong …

Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Dihydrogen complexation with retention of the H–H bond, once an exotic concept, has by
now appeared in a very wide range of contexts. Three structural types are currently …

Abstract The two‐coordinate [(CAAC) 2Fe] complex [CAAC= cyclic (alkyl)(amino) carbene]
binds dinitrogen at low temperature (T<− 80° C). The resulting putative three‐coordinate N2 …

Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

The synthesis of a cobalt dihydrogen CoI-(H2) complex prepared from a CoI-(N2) precursor
supported by a monoanionic pincer bis (carbene) ligand, MesCCC (MesCCC= bis (mesityl …

Many challenging chemical reactions require precious metal catalysts to proceed. Bio-
inspired catalysts featuring multiple earth-abundant metals are an attractive alternative, as …

Reversible, heterolytic addition of H2 across an iron–boron bond in a ferraboratrane with
formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These …