Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Recent development of pH-responsive polymers for cancer nanomedicine

H Tang, W Zhao, J Yu, Y Li, C Zhao - Molecules, 2018 - mdpi.com
Cancer remains a leading cause of death worldwide with more than 10 million new cases
every year. Tumor-targeted nanomedicines have shown substantial improvements of the …

Controlled-Radical Polymerization of α-Lipoic Acid: A General Route to Degradable Vinyl Copolymers

KR Albanese, PT Morris, J Read de Alaniz… - Journal of the …, 2023 - ACS Publications
Here, we present the synthesis and characterization of statistical and block copolymers
containing α-lipoic acid (LA) using reversible addition–fragmentation chain-transfer (RAFT) …

Photoinduced dithiolane crosslinking for multiresponsive dynamic hydrogels

BR Nelson, BE Kirkpatrick, CE Miksch… - Advanced …, 2024 - Wiley Online Library
While many hydrogels are elastic networks crosslinked by covalent bonds, viscoelastic
hydrogels with adaptable crosslinks are increasingly being developed to better recapitulate …

Building tunable degradation into high-performance poly (acrylate) pressure-sensitive adhesives

KR Albanese, Y Okayama, PT Morris, M Gerst… - ACS Macro …, 2023 - ACS Publications
Pressure-sensitive adhesives (PSAs) based on poly (acrylate) chemistry are common in a
wide variety of applications, but the absence of backbone degradability causes issues with …

Recent advances in the ring-opening polymerization of sulfur-containing monomers

VB Purohit, M Pięta, J Pietrasik, CM Plummer - Polymer Chemistry, 2022 - pubs.rsc.org
Inspired by the uniqueness of ring-opening polymerization and the ubiquity of sulfur-
containing heterocycles, much attention has been paid to the synthesis of sulfur-containing …

Digital light processing of dynamic bottlebrush materials

C Choi, Y Okayama, PT Morris… - Advanced Functional …, 2022 - Wiley Online Library
Bottlebrush elastomers have attracted significant attention as a class of super‐soft materials
with a storage modulus (G′) less than the intrinsic entanglement shear modulus (Ge), but …

Scalable Synthesis of Degradable Copolymers Containing α-Lipoic Acid via Miniemulsion Polymerization

PT Morris, K Watanabe, KR Albanese… - Journal of the …, 2024 - ACS Publications
A robust method is described to synthesize degradable copolymers under aqueous
miniemulsion conditions using α-lipoic acid as a cheap and scalable building block. Simple …

Injectable self-healing hydrogels formed via thiol/disulfide exchange of thiol functionalized F127 and dithiolane modified PEG

H Yu, Y Wang, H Yang, K Peng, X Zhang - Journal of Materials …, 2017 - pubs.rsc.org
Injectable self-healing hydrogels have found broad applications in drug delivery, tissue
engineering and controlled 3D cell culture. Recently, cyclic disulfides were found to be …

Disulfide-containing monomers in chain-growth polymerization

M Pięta, VB Purohit, J Pietrasik, CM Plummer - Polymer Chemistry, 2023 - pubs.rsc.org
Due to the significance of disulfide bonds within modern material and medicinal sciences,
much attention has been paid to the synthesis of disulfide-containing polymers. Within this …