Highly oxygenated organic molecules (HOM) from gas-phase autoxidation involving peroxy radicals: A key contributor to atmospheric aerosol

F Bianchi, T Kurtén, M Riva, C Mohr… - Chemical …, 2019 - ACS Publications
Highly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation
involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on …

Laboratory studies of organic peroxy radical chemistry: an overview with emphasis on recent issues of atmospheric significance

JJ Orlando, GS Tyndall - Chemical Society Reviews, 2012 - pubs.rsc.org
Organic peroxy radicals (often abbreviated RO2) play a central role in the chemistry of the
Earth's lower atmosphere. Formed in the atmospheric oxidation of essentially every organic …

A large source of low-volatility secondary organic aerosol

M Ehn, JA Thornton, E Kleist, M Sipilä, H Junninen… - Nature, 2014 - nature.com
Forests emit large quantities of volatile organic compounds (VOCs) to the atmosphere. Their
condensable oxidation products can form secondary organic aerosol, a significant and …

The formation, properties and impact of secondary organic aerosol: current and emerging issues

M Hallquist, JC Wenger, U Baltensperger… - Atmospheric …, 2009 - acp.copernicus.org
Secondary organic aerosol (SOA) accounts for a significant fraction of ambient tropospheric
aerosol and a detailed knowledge of the formation, properties and transformation of SOA is …

Atmospheric composition change–global and regional air quality

PS Monks, C Granier, S Fuzzi, A Stohl… - Atmospheric …, 2009 - Elsevier
Air quality transcends all scales with in the atmosphere from the local to the global with
handovers and feedbacks at each scale interaction. Air quality has manifold effects on …

Theoretical studies of atmospheric reaction mechanisms in the troposphere

L Vereecken, JS Francisco - Chemical Society Reviews, 2012 - pubs.rsc.org
The chemistry of the atmosphere encompasses a vast number of reactions acting on a
plethora of intermediates. These reactions, occurring sequentially and in parallel, give rise to …

Hydroxyl radical-induced formation of highly oxidized organic compounds

T Berndt, S Richters, T Jokinen, N Hyttinen… - Nature …, 2016 - nature.com
Explaining the formation of secondary organic aerosol is an intriguing question in
atmospheric sciences because of its importance for Earth's radiation budget and the …

The formation of highly oxidized multifunctional products in the ozonolysis of cyclohexene

MP Rissanen, T Kurten, M Sipila… - Journal of the …, 2014 - ACS Publications
The prompt formation of highly oxidized organic compounds in the ozonolysis of
cyclohexene (C6H10) was investigated by means of laboratory experiments together with …

New approach to the detection of short-lived radical intermediates

PJH Williams, GA Boustead, DE Heard… - Journal of the …, 2022 - ACS Publications
We report a new general method for trapping short-lived radicals, based on a homolytic
substitution reaction SH2′. This departure from conventional radical trapping by addition or …

Hydroxyl radical recycling in isoprene oxidation driven by hydrogen bonding and hydrogen tunneling: The upgraded LIM1 mechanism

J Peeters, JF Müller, T Stavrakou… - The Journal of Physical …, 2014 - ACS Publications
The Leuven isoprene mechanism, proposed earlier to aid in rationalizing the unexpectedly
high hydroxyl radical (OH) concentrations in isoprene-rich, low-nitric-oxide (NO) regions …