Microporous metal-organic framework materials for gas separation

RB Lin, S Xiang, W Zhou, B Chen - Chem, 2020 - cell.com
Gas separation is a very important industrial process for manufacturing chemicals, fuels,
plastics, and polymers but is also energy intensive through the traditional cryogenic …

Porous metal-organic frameworks for gas storage and separation: Status and challenges

H Li, L Li, RB Lin, W Zhou, Z Zhang, S Xiang, B Chen - EnergyChem, 2019 - Elsevier
Gases are widely used as energy resources for industry and our daily life. Developing
energy cost efficient porous materials for gas storage and separation is of fundamentally and …

Separating water isotopologues using diffusion-regulatory porous materials

Y Su, K Otake, JJ Zheng, S Horike, S Kitagawa, C Gu - Nature, 2022 - nature.com
The discovery of a method to separate isotopologues, molecular entities that differ in only
isotopic composition, is fundamentally and technologically essential but remains …

Creating optimal pockets in a clathrochelate-based metal–organic framework for gas adsorption and separation: Experimental and computational studies

W Gong, Y Xie, TD Pham, S Shetty… - Journal of the …, 2022 - ACS Publications
The rational design and synthesis of robust metal–organic frameworks (MOFs) based on
novel organic building blocks are fundamental aspects of reticular chemistry. Beyond simply …

Robust and radiation-resistant hofmann-type metal–organic frameworks for record xenon/krypton separation

J Pei, XW Gu, CC Liang, B Chen, B Li… - Journal of the American …, 2022 - ACS Publications
The discovery of high-performance adsorbents for highly efficient separation of xenon from
krypton is an important but challenging task in the chemical industry due to their similar size …

Tunable confined aliphatic pore environment in robust metal–organic frameworks for efficient separation of gases with a similar structure

J Zhou, T Ke, F Steinke, N Stock, Z Zhang… - Journal of the …, 2022 - ACS Publications
The fine-tuning of the pore structure of metal–organic frameworks (MOFs) is of critical
importance to developing energy-efficient processes for the challenging separation of …

Programmed polarizability engineering in a cyclen-based cubic Zr (IV) metal–organic framework to boost Xe/Kr Separation

W Gong, Y Xie, X Wang, KO Kirlikovali… - Journal of the …, 2023 - ACS Publications
Efficient separation of xenon (Xe) and krypton (Kr) mixtures through vacuum swing
adsorption (VSA) is considered the most attractive route to reduce energy consumption, but …

Inverse CO2/C2H2 separation in a pillared-layer framework featuring a chlorine-modified channel by quadrupole-moment sieving

XY Li, Y Song, CX Zhang, CX Zhao, C He - Separation and Purification …, 2021 - Elsevier
Selective isolation of CO 2 from C 2 H 2 using CO 2-selective adsorbent is a huge challenge
due to their analogous physical properties as well as molecular sizes and shapes. In this …

The chemistry of reticular framework nanoparticles: MOF, ZIF, and COF materials

E Ploetz, H Engelke, U Lächelt… - Advanced Functional …, 2020 - Wiley Online Library
Nanoparticles have become a vital part of a vast number of established processes and
products; they are used as catalysts, in cosmetics, and even by the pharmaceutical industry …

Rational design and synthesis of ultramicroporous metal-organic frameworks for gas separation

T Wang, E Lin, YL Peng, Y Chen, P Cheng… - Coordination Chemistry …, 2020 - Elsevier
Metal-organic frameworks (MOFs) have emerged as a new generation of porous materials
that demonstrate great promise in diverse application fields, especially gas separation, due …