Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Synthesis and functionalization of porphyrins through organometallic methodologies

S Hiroto, Y Miyake, H Shinokubo - Chemical reviews, 2017 - ACS Publications
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

Iron-catalyzed transformations of diazo compounds

SF Zhu, QL Zhou - National Science Review, 2014 - academic.oup.com
Although iron-promoted diazo transformations were only discovered during the 1990s, iron
can undergo facile changes in its oxidation state and possesses distinct Lewis acid …

Iron: A worthy contender in metal carbene chemistry

VF Batista, DC GA Pinto, AMS Silva - ACS Catalysis, 2020 - ACS Publications
Carbene transfer reactions hold a pivotal role in organic synthesis, allowing the prompt
construction of complex molecules from accessible reagents. Iron complexes emerged as …

S, O-ligand-promoted palladium-catalyzed C–H functionalization reactions of nondirected arenes

K Naksomboon, C Valderas, M Gómez-Martínez… - ACS …, 2017 - ACS Publications
Pd (II)-catalyzed C–H functionalization of nondirected arenes has been realized using an
inexpensive and easily accessible type of bidentate S, O-ligand. The catalytic system shows …

“Click”-reaction: An alternative tool for new architectures of porphyrin based derivatives

K Ladomenou, V Nikolaou, G Charalambidis… - Coordination Chemistry …, 2016 - Elsevier
The copper catalyzed azide-alkyne cycloaddition (CuAAC), known as “click reaction” is a
well-known method used for the construction of complex molecular architectures. Due to its …

Synthesis, characterization, and reactivities of high valent metal–corrole (M= Cr, Mn, and Fe) complexes

S Mondal, PK Naik, JK Adha, S Kar - Coordination Chemistry Reviews, 2019 - Elsevier
For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …

A phosphonium ylide as an ionic nucleophilic catalyst for primary hydroxyl group selective acylation of diols

Y Toda, T Sakamoto, Y Komiyama, A Kikuchi… - ACS …, 2017 - ACS Publications
Carbonyl-stabilized phosphonium ylides exhibit great utility in modern organic synthesis,
and they are known as an ambident nucleophile at the carbonyl oxygen atom and at the α …

Phosphonium ylide catalysis: a divergent diastereoselective approach to synthesize cyclic ketene acetals [thia (zolidines/zinanes)] from β-ketothioamides and …

MA Ansari, D Yadav, S Soni, MS Singh - Organic & biomolecular …, 2019 - pubs.rsc.org
Phosphonium ylides are being reported here as a catalyst for the formation of thiazolidines
and 1, 3-thiazinanes from β-ketothioamides (which act as a three atom N, C, and S synthon) …

Application of CuAAC for the covalent immobilization of homogeneous catalysts

AE Fernandes, AM Jonas, O Riant - Tetrahedron, 2014 - Elsevier
The development of sustainable catalysts that can combine advantages from both
homogeneous and heterogeneous catalysis has raised considerable promises over the last …