Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching,“Cocktails” of catalysts and dynamic systems

DB Eremin, VP Ananikov - Coordination Chemistry Reviews, 2017 - Elsevier
In the present review, we consider the transformations of molecular catalysts, leaching,
aggregation and various interconversions of metal complexes, clusters and nanoparticles …

Beyond click chemistry–supramolecular interactions of 1, 2, 3-triazoles

B Schulze, US Schubert - Chemical Society Reviews, 2014 - pubs.rsc.org
The research on 1, 2, 3-triazoles has been lively and ever-growing since its stimulation by
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …

Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure

RH Crabtree - Chemical reviews, 2015 - ACS Publications
Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

The role of palladium nanoparticles in catalytic C–C cross-coupling reactions

AM Trzeciak, AW Augustyniak - Coordination Chemistry Reviews, 2019 - Elsevier
This review describes the recent advances in understanding of the mechanism of palladium
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …

Application of 1, 2, 3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond

KF Donnelly, A Petronilho, M Albrecht - Chemical Communications, 2013 - pubs.rsc.org
Triazolylidenes have rapidly emerged as a powerful subclass of N-heterocyclic carbene
ligands for transition metals. They are readily available through regioselective [2+ 3] …

Metal Complexes of Click‐Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

D Schweinfurth, L Hettmanczyk… - … für anorganische und …, 2017 - Wiley Online Library
Even though the existence of 1, 2, 3‐triazoles has been known for more than a century, the
recent discovery of a copper (I) catalyzed version of this reaction has attributed …

A new mode of operation of Pd-NHC systems studied in a catalytic Mizoroki–Heck reaction

AV Astakhov, OV Khazipov, AY Chernenko… - …, 2017 - ACS Publications
Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the
system of choice for homogeneous catalysis with well-defined molecular active species due …

Catalysis by 1, 2, 3-triazole-and related transition-metal complexes

D Huang, P Zhao, D Astruc - Coordination Chemistry Reviews, 2014 - Elsevier
A short overview of the multiple coordination modes of 1, 2, 3-triazole-and related transition-
metal complexes are provided, then the implication of and catalysis with transition-metal-1 …

Novel morpholine liganded Pd-based N-heterocyclic carbene complexes: Synthesis, characterization, crystal structure, antidiabetic and anticholinergic properties

A Aktaş, DB Celepci, R Kaya, P Taslimi, Y Gök… - Polyhedron, 2019 - Elsevier
This study involves the synthesis of novel N-heterocyclic carbene (NHC) PdX 2 (morpholine)
complexes (1a–i). These Pd-based complexes are synthesized from pyridine enhanced …