Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Recent applications of homogeneous catalysis in electrochemical organic synthesis

X Cheng, A Lei, TS Mei, HC Xu, K Xu… - CCS Chemistry, 2022 - chinesechemsoc.org
Although the combination of electrochemistry and homogeneous catalysis has proven to be
a powerful strategy for achieving a diverse array of novel transformations, some challenges …

Electrochemical Syntheses of Polycyclic Aromatic Hydrocarbons (PAHs)

Y Wang, R Zhao, L Ackermann - Advanced Materials, 2023 - Wiley Online Library
Polycyclic aromatic hydrocarbons (PAHs) have surfaced as increasingly viable components
in optoelectronics and material sciences. The development of highly efficient and atom …

Distal Ruthenaelectro‐Catalyzed meta‐C−H Bromination with Aqueous HBr

Y Wang, H Simon, X Chen, Z Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
While electrochemical ortho‐selective C− H activations are well established, distal C− H
activations continue to be underdeveloped. In contrast, we herein describe the …

Electrolytic C–H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

S Jin, J Kim, D Kim, JW Park, S Chang - ACS Catalysis, 2021 - ACS Publications
Herein, we describe the development of a Rh-catalyzed C–H acyloxylation under mild
electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was …

Silver‐Free C− H Activation: Strategic Approaches towards Realizing the Full Potential of C− H Activation in Sustainable Organic Synthesis

A Mondal, M van Gemmeren - … Chemie International Edition, 2022 - Wiley Online Library
The activation of carbon− hydrogen bonds is considered as one of the most attractive
techniques in synthetic organic chemistry because it bears the potential to shorten synthetic …

Scalable selective electrochemical oxidation of sulfides to sulfoxides

ZH Fu, HD Tian, SF Ni, JS Wright, M Li, LR Wen… - Green …, 2022 - pubs.rsc.org
An electrochemical protocol for the selective oxidation of sulfides to sulfoxides has been
developed in which NaCl plays a dual role:(1) as an electrolyte for the electrochemical …

Electrochemically-mediated C–H functionalization of allenes and 1, 3-dicarbonyl compounds to construct tetrasubstituted furans

MX He, Y Yao, CZ Ai, ZY Mo, YZ Wu, Q Zhou… - Organic Chemistry …, 2022 - pubs.rsc.org
C–H functionalization of allenes is an available strategy to construct heterocyclic
compounds. Herein we propose a sus-tainable electrocatalytic C–H activation for the …

Visible-Light-Induced Difluoroalkylation of 1-(Allyloxy)-2-(1-arylvinyl) benzenes and 1-(1-Arylvinyl)-2-(vinyloxy) benzenes: Synthesis of Bis-Difluoroalkylated …

N Zhou, Z Xia, K Kuang, Q Xu, F Zhao, L Wang… - Organic …, 2022 - ACS Publications
A novel visible-light-mediated difluoroalkylation of 1-(allyloxy)-2-(1-arylvinyl) benzenes and
1-(1-arylvinyl)-2-(vinyloxy) benzenes for the synthesis of bis-difluoroalkylated benzoxepines …