Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

Herein, we report a facile, efficient, and practical protocol that enables the preparation of aryl
xanthates and aryl dithiocarbamates from functionalized dibenzothiophenium salts via a …

We report a photoredox system comprising sodium iodide, triphenyl phosphine, and N, N,
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …

We report an organophotoredox-catalyzed stereoselective allylic arylation of MBH acetates
with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted …

A photoredox-catalyzed direct arylation of quinoxalin-2-(1 H)-ones using diaryliodonium
triflates as the convenient, stable, and cheap aryl source is described. A broad variety of …

The aryl O-carbamate (ArOAm) group is among the strongest of the directed metalation
groups (DMGs) in directed ortho metalation (D o M) chemistry, especially in the form Ar …

Preparation of S-aryl xanthates via transition-metal-catalyzed or SNAr reactions is
complicated by their further transformations under the utilized conditions. In contrast, S …

A convenient and practical strategy was developed for the synthesis of carbamo
(dithioperoxo) thioates through the simple dehydrogenation coupling of thiols and amines …

Herein, a multicomponent, environmentally friendly protocol for generating di-aryl
dithiocarbamates was developed effectively from readily available thianthrenium salts. The …

A facile synthesis of biologically important S-aryl dithiocarbamates has been demonstrated
by the aryne three-component coupling involving CS2 and aliphatic amines. This transition …