Transition metal-mediated cycloaddition reactions

M Lautens, W Klute, W Tam - Chemical reviews, 1996 - ACS Publications
The discovery and development of new chemical reactions is a major focus of research
activity in organic chemistry. The chemical synthesis of molecules provided by Nature has …

Carbenes: Synthesis, properties, and organometallic chemistry

P De Fremont, N Marion, SP Nolan - Coordination Chemistry Reviews, 2009 - Elsevier
Carbenes, thought of only as transient species for a long time, have become ubiquitous in
organometallic chemistry. Their interaction with a metal center, which allows for their …

[图书][B] Catalytic asymmetric synthesis

T Akiyama, I Ojima - 2022 - books.google.com
Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most
important catalytic asymmetric reactions known today This book covers the preparation of …

Metal-mediated synthesis of medium-sized rings

L Yet - Chemical reviews, 2000 - ACS Publications
The importance of medium-and large-sized rings in organic chemistry is exemplified by their
being the structural core of a large number of biologically important natural products1 and …

Cascade processes of metallo carbenoids

A Padwa, MD Weingarten - Chemical reviews, 1996 - ACS Publications
A major challenge in organic synthesis today is to devise reactions that can form several
carbon-carbon bonds in one operation leading to the construction of polycyclic structures …

Ylide formation from the reaction of carbenes and carbenoids with heteroatom lone pairs

A Padwa, SF Hornbuckle - Chemical Reviews, 1991 - ACS Publications
Ylides can be viewed as species in which a positively charged heteroatom is connected to a
carbon atom possessing an unshared pair of electrons. These reactive intermediates are …

Transition metal-catalyzed carbocyclizations in organic synthesis

I Ojima, M Tzamarioudaki, Z Li, RJ Donovan - Chemical reviews, 1996 - ACS Publications
Carbocyclizations of alkenes and alkynes are extremely important and useful reactions for
the syntheses of a variety of carbocyclic and heterocyclic compounds. The term …

A bonding model for gold(I) carbene complexes

D Benitez, ND Shapiro, E Tkatchouk, Y Wang… - Nature …, 2009 - nature.com
The last decade has witnessed dramatic growth in the number of reactions catalysed by
electrophilic gold complexes. Although proposed mechanisms often invoke the intermediacy …

Nitrogen donors in organometallic chemistry and homogeneous catalysis

A Togni, LM Venanzi - Angewandte Chemie International …, 1994 - Wiley Online Library
Homogeneous catalysis has been responsible for many major recent developments in
synthetic organic chemistry. The combined use of organometallic and coordination …

Intermolecular metal‐catalyzed carbenoid cyclopropanations

HML Davies, EG Antoulinakis - Organic reactions, 2004 - Wiley Online Library
The metal‐catalyzed decomposition of diazo compounds in the presence of alkenes is a
well‐established reaction. Since the original Organic Reactions review on the reaction of …