Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Multicomponent reactions and photo/electrochemistry join forces: atom economy meets energy efficiency

GA Coppola, S Pillitteri, EV Van der Eycken… - Chemical Society …, 2022 - pubs.rsc.org
Visible-light photoredox catalysis has been regarded as an extremely powerful tool in
organic chemistry, bringing the spotlight back to radical processes. The versatility of …

Transition metal (Ni, Cu, Pd)-catalyzed alkene dicarbofunctionalization reactions

LM Wickham, R Giri - Accounts of chemical research, 2021 - ACS Publications
Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel

S Zhu, X Zhao, H Li, L Chu - Chemical Society Reviews, 2021 - pubs.rsc.org
The catalytic dicarbofunctionalization of unsaturated π bonds represents a powerful platform
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …

Nickel-catalyzed dicarbofunctionalization of alkenes

X Qi, T Diao - ACS catalysis, 2020 - ACS Publications
1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

Dual nickel/photoredox-catalyzed asymmetric carbosulfonylation of alkenes

X Du, I Cheng-Sánchez, C Nevado - Journal of the American …, 2023 - ACS Publications
An asymmetric three-component carbosulfonylation of alkenes is presented here. The
reaction, involving the simultaneous formation of a C–C and a C–S bond across the π …

Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes

J Derosa, O Apolinar, T Kang, VT Tran, KM Engle - Chemical Science, 2020 - pubs.rsc.org
Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a
powerful tool for forging two C–C bonds in a single reaction. Building upon the powerful …

Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis

C Rao, T Zhang, H Liu, H Huang - Nature Catalysis, 2023 - nature.com
Selective construction of two distinct alkyl–alkyl bonds across the C= C bond of simple
unactivated olefins is a persistent challenge in organic synthesis. Transition metal-catalysed …

Recent advances in photoredox and nickel dual-catalyzed cascade reactions: pushing the boundaries of complexity

C Zhu, H Yue, L Chu, M Rueping - Chemical science, 2020 - pubs.rsc.org
Cascade reactions that produce multiple chemical bonds in one synthetic operation are
important in the efficient construction of complex molecules. In addition, photoredox and …