Metal-ligand dual-site single-atom nanozyme mimicking urate oxidase with high substrates specificity

K Wang, Q Hong, C Zhu, Y Xu, W Li, Y Wang… - Nature …, 2024 - nature.com
In nature, coenzyme-independent oxidases have evolved in selective catalysis using
isolated substrate-binding pockets. Single-atom nanozymes (SAzymes), an emerging type of …

Metal–organic framework derived micro-/nano-materials: precise synthesis and clean energy applications

G Zhang, X Li, Y Liu, G Du, H Pang - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
Metal–organic frameworks (MOFs) and their derived materials have emerged as leading
contenders in the realm of advanced materials science, heralded for their versatility, high …

Atomic Engineering of Single‐Atom Nanozymes for Biomedical Applications

J Shen, J Chen, Y Qian, X Wang, D Wang… - Advanced …, 2024 - Wiley Online Library
Single‐atom nanozymes (SAzymes) showcase not only uniformly dispersed active sites but
also meticulously engineered coordination structures. These intricate architectures bestow …

Constructing Co4(SO4)4 Clusters within Metal–Organic Frameworks for Efficient Oxygen Electrocatalysis

Z Liang, G Zhou, H Tan, Y Mou, J Zhang… - Advanced …, 2024 - Wiley Online Library
Multinuclear metal clusters are ideal candidates to catalyze small molecule activation
reactions involving the transfer of multiple electrons. However, synthesizing active metal …

Geometric tuning of coordinatively unsaturated copper (I) sites in metal–organic frameworks for ambient-temperature hydrogen storage

Y Yabuuchi, H Furukawa, KM Carsch… - Journal of the …, 2024 - ACS Publications
Porous solids can accommodate and release molecular hydrogen readily, making them
attractive for minimizing the energy requirements for hydrogen storage relative to physical …

Regulating Reactive Oxygen Intermediates of Fe− N− C SAzyme via Second‐Shell Coordination for Selective Aerobic Oxidation Reactions

Y Xu, Y Ma, X Chen, K Wu, K Wang, Y Shen… - Angewandte …, 2024 - Wiley Online Library
Reactive oxygen species (ROS) regulation for single‐atom nanozymes (SAzymes), eg, Fe−
N− C, is a key scientific issue that determines the activity, selectivity, and stability of aerobic …

High-temperature carbon dioxide capture in a porous material with terminal zinc hydride sites

RC Rohde, KM Carsch, MN Dods, HZH Jiang… - Science, 2024 - science.org
Carbon capture can mitigate point-source carbon dioxide (CO2) emissions, but hurdles
remain that impede the widespread adoption of amine-based technologies. Capturing CO2 …

Selective adsorption of oxygen from humid air in a metal–organic framework with trigonal pyramidal copper (I) sites

KM Carsch, AJ Huang, MN Dods… - Journal of the …, 2024 - ACS Publications
High or enriched-purity O2 is used in numerous industries and is predominantly produced
from the cryogenic distillation of air, an extremely capital-and energy-intensive process …

Surface Chemistry Regulation in Cu4I4-Triazolate Metal–Organic Frameworks for One-Step C3H6 Purification from Quaternary C3 Mixtures

XJ Xie, ZH Zhang, QY Cao, YL Huang… - Journal of the …, 2024 - ACS Publications
C3H6 is a crucial building block for many chemicals, yet separating it from other C3
hydrocarbons presents a significant challenge. Herein, we report a hydrolytically stable …

Energy transfer-mediated multiphoton synergistic excitation for selective C(sp3)–H functionalization with coordination polymer

Z Wang, Y Tang, S Liu, L Zhao, H Li, C He… - Nature …, 2024 - nature.com
Activation and selective oxidation of inert C (sp 3)–H bonds remain one of the most
challenging tasks in current synthetic chemistry due to the inherent inertness of C (sp 3)–H …