In this critical review, the strategic and economic benefits of C–H functionalization logic will
be analyzed through the critical lens of total synthesis. In order to illustrate the dramatically …

C H oxidation has a long history and an ongoing presence in research at the forefront of
chemistry and interrelated fields. As such, numerous highly useful articles and reviews have …

New methods and strategies for the direct functionalization of C–H bonds are beginning to
reshape the field of retrosynthetic analysis, affecting the synthesis of natural products …

This critical review discusses historical and contemporary research in the field of transition
metal-catalyzed carbon–hydrogen (C–H) bond activation through the lens of …

The mixed-valent paddlewheel complex tetrakis (2-oxypyridinato) diruthenium (II, III)
chloride,[Ru2 (hp) 4Cl], catalyzes intramolecular allylic C–H amination with bis (homoallylic) …

Simulation of the function of cytochrome P-450 with low valent ruthenium complex catalysts
leads to the discovery of biomimetic, catalytic oxidation of various substrates selectively …

A widely applicable, practical, and scalable synthetic method for efficient ene‐type double
oxidation of alkenes is reported via a two‐step alkenyl thianthrenium umpolung/Kornblum …

Dirhodium compounds are emerging as highly efficient catalysts for diverse reactions, and
those with carboxamidate ligands have the broadest applications. The unique features of …

Abstract Die C‐H‐Oxidation hat eine lange Geschichte und ist seit jeher Teil der
Spitzenforschung in der Chemie und verwandten Gebieten. Folgerichtig wurde bereits eine …

The first and asymmetric total synthesis of longeracinphyllin A, a hexacyclic Daphniphyllum
alkaloid, has been accomplished. A tetracyclic intermediate was prepared through silver …