Recent progress in methanol‐to‐olefins (MTO) catalysts

M Yang, D Fan, Y Wei, P Tian, Z Liu - Advanced materials, 2019 - Wiley Online Library
Methanol conversion to olefins, as an important reaction in C1 chemistry, provides an
alternative platform for producing basic chemicals from nonpetroleum resources such as …

Recent advances of the nano-hierarchical SAPO-34 in the methanol-to-olefin (MTO) reaction and other applications

J Zhong, J Han, Y Wei, P Tian, X Guo… - Catalysis Science & …, 2017 - pubs.rsc.org
The recent advances in synthesis and catalytic applications of nano-hierarchical SAPO-34
for methanol-to-olefin (MTO) conversion and other reactions have been elaborated in this …

The state-of-the-art synthetic strategies for SAPO-34 zeolite catalysts in methanol-to-olefin conversion

Q Sun, Z Xie, J Yu - National Science Review, 2018 - academic.oup.com
ABSTRACT Methanol-to-olefin (MTO) conversion has proven to be one of the most
successful non-petrochemical routes for producing light olefins. Silicoaluminophosphate …

Down the microporous rabbit hole of silicoaluminophosphates: Recent developments on synthesis, characterization, and catalytic applications

ME Potter - ACS Catalysis, 2020 - ACS Publications
Since their invention silicoaluminophosphates (SAPOs) have become by far the most
researched class of aluminophosphates due to their commercial use as solid acid catalysts …

Conversion of methanol to olefins: stabilization of nanosized SAPO-34 by hydrothermal treatment

Z Li, J Martínez-Triguero, J Yu, A Corma - Journal of Catalysis, 2015 - Elsevier
Abstract Nano-SAPO-34 zeolite catalyst (20 nm crystal size) has been stabilized by
hydrothermal treatment. After steamed at high temperatures (T⩾ 550° C), its textural …

Effect of framework topology of SAPO catalysts on selectivity and deactivation profile in the methanol-to-olefins reaction

I Pinilla-Herrero, U Olsbye, C Márquez-Álvarez… - Journal of catalysis, 2017 - Elsevier
Catalytic performance in the methanol-to-olefins reaction was studied on four 8-ring
silicoaluminophosphate (SAPO) molecular sieves with different framework topologies and …

Synthesis of nano-sized SAPO-34 with morpholine-treated micrometer-seeds and their catalytic performance in methanol-to-olefin reactions

C Sun, Y Wang, A Zhao, X Wang, C Wang… - Applied Catalysis A …, 2020 - Elsevier
Uniformly nano-sized SAPO-34 zeotypes were synthesized using morpholine (MOR)-treated
micrometer-sized SAPO-34 (MS-SAPO-34) seeds and MOR as the template. The samples …

Carbon nanotube templated synthesis of metal containing hierarchical SAPO-34 catalysts: impact of the preparation method and metal avidities in the MTO reaction

AZ Varzaneh, J Towfighi, S Sahebdelfar - Microporous and Mesoporous …, 2016 - Elsevier
Hierarchical SAPO-34 was synthesized hydrothermally using carbon nanotube as hard
template and modified with Co and Ni by isomorphous substitution and impregnation …

Insights into the catalytic cycle and activity of methanol-to-olefin conversion over low-silica AlPO-34 zeolites with controllable Brønsted acid density

W Dai, G Cao, L Yang, G Wu, M Dyballa… - Catalysis Science & …, 2017 - pubs.rsc.org
Low-silica AlPO-34 materials with similar crystal sizes but different Brønsted acid site
densities were prepared and investigated as catalysts in methanol-to-olefin (MTO) …

Uncovering the role of Lewis and Brønsted acid sites in perforated SAPO-34 with an enhanced lifetime in methanol conversion to light olefins

M Ghavipour, TJ Goncalves, R Al Hussami… - New Journal of …, 2023 - pubs.rsc.org
Although the micropores of SAPO-34 (the catalyst in the conversion of methanol to light
olefins) favor higher light olefins selectivity, they are vulnerable to blockage by coke, which …