Borates: A rich source for optical materials

M Mutailipu, KR Poeppelmeier, S Pan - Chemical Reviews, 2020 - ACS Publications
The primary goal of this review is to present a clear chemical perspective of borates in order
to stimulate and facilitate the discovery of new borate-based optical materials. These …

High‐Pressure/High‐Temperature Synthesis of LnB3.6O7 (Ln=La, Pr) – Two Unique Lanthanoid Borates in a Defective α‐SrB4O7‐Structure‐Type

TA Teichtmeister, I Widmann… - European Journal of …, 2024 - Wiley Online Library
The orthorhombic phases LaB3. 6O7 and PrB3. 6O7 were obtained by high‐pressure/high‐
temperature syntheses at 11 GPa and temperatures of 1130° C (LaB3. 6O7) as well as 850° …

Pentacoordinated silicon in the high-pressure modification of datolite, CaBSiO 4 (OH)

LA Gorelova, AS Pakhomova, G Aprilis… - Inorganic Chemistry …, 2018 - pubs.rsc.org
A new modification of borosilicate datolite, CaBSiO4 (OH), has been discovered using
synchrotron-based in situ high-pressure single-crystal X-ray diffraction. The phase transition …

Crystal structure re‐determination, spectroscopy, and photoluminescence of π‐YBO3:Eu3+

B Fuchs, F Schröder, G Heymann… - Zeitschrift für …, 2021 - Wiley Online Library
To unambiguously clarify the long‐debated crystal structure of the low‐temperature
orthoborate π‐YBO3, single‐crystals of the europium‐doped π‐YBO3: Eu3+ were prepared …

First-Principles investigation of Pressure-Induced structural transformations of barium borates in the BaO-B2O3-BaF2 system in the range of 0–10 GPa

NE Sagatov, TB Bekker, IV Podborodnikov… - Computational Materials …, 2021 - Elsevier
First-principles calculations within the density functional theory of the stability of barium
borates of the BaO-B 2 O 3-BaF 2 ternary system have been performed at the pressure of up …

Pr3Mo4B6O24(OH)3: High‐Pressure/High‐Temperature Synthesis of an Acentric Rare Earth Molybdenum Borate

TA Teichtmeister, L Bayarjargal, K Wurst… - European Journal of …, 2023 - Wiley Online Library
We report on the synthesis of a new praseodymium molybdenum borate under high‐
pressure/high‐temperature conditions. The new compound with the sum formula …

High-pressure synthesis and crystal structure of α-Y2B4O9

MK Schmitt, H Huppertz - Zeitschrift für Naturforschung B, 2017 - degruyter.com
Abstract α-Y2B4O9 was synthesized in a high-pressure/high-temperature experiment at 12.3
GPa/1020° C. The crystal structure has been determined via single-crystal X-ray diffraction …

Expanding transition metal borate chemistry to include main group elements: high-pressure synthesis and structural relation of β-MgB4O7

LC Pasqualini, H Huppertz - Zeitschrift für Naturforschung B, 2023 - degruyter.com
The high-pressure/high-temperature synthesis of β-MgB4O7 at 9 GPa and 1200° C is
presented. The determination of its crystal structure by single-crystal X-ray diffraction has …

Synthesis and Crystal Structure of the Acentric Indium Borate InB6O9(OH)3

D Vitzthum, L Bayarjargal, B Winkler… - Inorganic …, 2018 - ACS Publications
The new acentric indium borate InB6O9 (OH) 3 was synthesized in a Walker-type multianvil
apparatus at extreme pressure and temperature conditions of 12.3 GPa and 1500° C. Single …

Formation Mechanism of a Polyanonic Framework from Layer to Chain Explored by Adjusting Time, Temperature, and pH: Preparation and Characterization of Metal …

JX Deng, ZQ Liu, CY Pan, Y Liu, J Li, FH Zhao… - Inorganic …, 2019 - ACS Publications
The first column of two-dimensional (2D)-layered metal-complex-templated nickel borate
was obtained by using a solvothermal synthesis method. The 2D nickel borate [Ni (en) …