Conspectus The widespread presence of hydrocarbons makes C–H functionalization an
attractive alternative to traditional cross-coupling methods. As indole is an important …

Indole is one of the most important heterocycles in organic synthesis, natural products, and
drug discovery. Recently, tremendous advances in the selective functionalization of indoles …

Enantioenriched organoboron intermediates are important building blocks in organic
synthesis and drug discovery. Recently, transition metal-catalyzed enantioselective 1, 2 …

Constructing photocatalyst systems to functionalize the inert C− H bonds has attracted
extensive research interest. However, purposeful modulation of interfacial charge transfer in …

Herein, we report a synthesis of cyclohexanones bearing multi‐continuous stereocenters by
combining copper‐catalyzed asymmetric conjugate addition of dialkylzinc reagents to cyclic …

We describe cooperative bimetallic catalysis that enables regio‐/stereodivergent asymmetric
α‐allylations of aldimine esters. By employing Et3B as the key activator, racemic allylic …

Over the last two decades, transition-metal catalyzed C–H functionalization of indoles has
emerged as an area of extensive research and tremendous progress has been made in this …

Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …

Enantioselective allylic substitution is one of the most important and reliable reactions for the
synthesis of chiral building blocks. While various transition metal catalysts have been …

A (MeDalphos) AuCl complex was found to efficiently catalyze the cross-coupling of indoles
and allyl acetates/alcohols. The reaction tolerates many functional groups and selectively …