Towards chemistry at absolute zero

BR Heazlewood, TP Softley - Nature Reviews Chemistry, 2021 - nature.com
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …

Bimolecular chemistry in the ultracold regime

Y Liu, KK Ni - Annual review of physical chemistry, 2022 - annualreviews.org
Advances in atomic, molecular, and optical physics techniques allowed the cooling of simple
molecules down to the ultracold regime (1 mK) and opened opportunities to study chemical …

Resonant collisional shielding of reactive molecules using electric fields

K Matsuda, L De Marco, JR Li, WG Tobias, G Valtolina… - Science, 2020 - science.org
Full control of molecular interactions, including reactive losses, would open new frontiers in
quantum science. We demonstrate extreme tunability of ultracold chemical reaction rates by …

Precision test of statistical dynamics with state-to-state ultracold chemistry

Y Liu, MG Hu, MA Nichols, D Yang, D Xie, H Guo… - Nature, 2021 - nature.com
Chemical reactions represent a class of quantum problems that challenge both the current
theoretical understanding and computational capabilities. Reactions that occur at ultralow …

Control of reactive collisions by quantum interference

H Son, JJ Park, YK Lu, AO Jamison, T Karman… - Science, 2022 - science.org
In this study, we achieved magnetic control of reactive scattering in an ultracold mixture of
23Na atoms and 23Na6Li molecules. In most molecular collisions, particles react or are lost …

Field-linked resonances of polar molecules

XY Chen, A Schindewolf, S Eppelt, R Bause, M Duda… - Nature, 2023 - nature.com
Scattering resonances are an essential tool for controlling the interactions of ultracold atoms
and molecules. However, conventional Feshbach scattering resonances, which have been …

Ultracold chemistry as a testbed for few-body physics

T Karman, M Tomza, J Pérez-Ríos - Nature Physics, 2024 - nature.com
Ultracold atoms, molecules and ions provide a unique playground to explore chemistry at
ultracold temperatures. In this Review, we discuss what makes these systems particularly …

Cold and ultracold molecules in the twenties

TP Softley - Proceedings of the Royal Society A, 2023 - royalsocietypublishing.org
A diversity of experimental techniques has been developed over the last 25 years to create
samples of molecular gases at temperatures close to the Absolute Zero—here we consider …

Quantum state–resolved molecular dipolar collisions over four decades of energy

G Tang, M Besemer, S Kuijpers, GC Groenenboom… - Science, 2023 - science.org
Collisions between cold polar molecules represent a fascinating research frontier but have
proven hard to probe experimentally. We report measurements of inelastic cross sections for …

Nuclear spin conservation enables state-to-state control of ultracold molecular reactions

MG Hu, Y Liu, MA Nichols, L Zhu, G Quéméner… - Nature Chemistry, 2021 - nature.com
Quantum-state control of reactive systems has enabled microscopic probes of underlying
interaction potentials and the alteration of reaction rates using quantum statistics. However …