Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Light in gold catalysis

S Witzel, ASK Hashmi, J Xie - Chemical Reviews, 2021 - ACS Publications
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Carbon–Germanium Bond Formation via Low-Valent Cobalt-Catalyzed Cross-Electrophile Coupling

H Chen, C Zhu, H Yue, M Rueping - ACS Catalysis, 2023 - ACS Publications
An efficient, electrochemically induced cobalt-catalyzed carbon–germanium bond formation
provides access to a variety of functionalized germane-containing compounds, including …

Organogermanes as orthogonal coupling partners in synthesis and catalysis

C Fricke, F Schoenebeck - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Since the advent of metal-catalyzed cross-coupling technology more than 40
years ago, the field has grown to be ever-increasingly enabling, yet the employed coupling …

Catalysis with Palladium (I) Dimers

C Fricke, T Sperger, M Mendel… - Angewandte Chemie …, 2021 - Wiley Online Library
Dinuclear PdI complexes have found widespread applications as diverse catalysts for a
multitude of transformations. Initially their ability to function as pre‐catalysts for low …

Recent Developments with Organogermanes: their Preparation and Application in Synthesis and Catalysis

T Rogova, E Ahrweiler, MD Schoetz… - Angewandte …, 2024 - Wiley Online Library
Within the sphere of traditional Pd0/PdII cross coupling reactions, organogermanes have
been historically outperformed both in terms of scope and reactivity by more conventional …

Catalytic ipso‐Nitration of Organosilanes Enabled by Electrophilic N‐Nitrosaccharin Reagent

I Mosiagin, AJ Fernandes, A Budinská… - Angewandte …, 2023 - Wiley Online Library
Nitroaromatic compounds represent one of the essential classes of molecules that are
widely used as feedstock for the synthesis of intermediates, the preparation of nitro‐derived …

cis-Selective Hydrogenation of Aryl Germanes: A Direct Approach to Access Saturated Carbo- and Heterocyclic Germanes

A Kaithal, HS Sasmal, S Dutta, F Schäfer… - Journal of the …, 2023 - ACS Publications
A catalytic approach of synthesizing the cis-selective saturated carbo-and heterocyclic
germanium compounds (3D framework) is reported via the hydrogenation of readily …

Modularity in the Csp3 Space─Alkyl Germanes as Orthogonal Molecular Handles for Chemoselective Diversification

A Selmani, MD Schoetz, AE Queen… - ACS Catalysis, 2022 - ACS Publications
To meet the need for a rapid, streamlined, and potentially automatable molecule synthesis,
modular coupling approaches are highly desired. While the diversification of aromatic …