Spin hyperpolarization in modern magnetic resonance

J Eills, D Budker, S Cavagnero, EY Chekmenev… - Chemical …, 2023 - ACS Publications
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …

Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR

T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …

[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …

Overhauser effects in insulating solids

TV Can, MA Caporini, F Mentink-Vigier… - The Journal of …, 2014 - pubs.aip.org
BACKGROUND Part of our results (vide infra) share a characteristic feature with the
Overhauser effect in solution where an enhancement is observed around the electron …

Nuclear depolarization and absolute sensitivity in magic-angle spinning cross effect dynamic nuclear polarization

F Mentink-Vigier, S Paul, D Lee, A Feintuch… - Physical Chemistry …, 2015 - pubs.rsc.org
Over the last two decades solid state Nuclear Magnetic Resonance has witnessed a
breakthrough in increasing the nuclear polarization, and thus experimental sensitivity, with …

Computationally assisted design of polarizing agents for dynamic nuclear polarization enhanced NMR: the AsymPol family

F Mentink-Vigier, I Marin-Montesinos… - Journal of the …, 2018 - ACS Publications
We introduce a new family of highly efficient polarizing agents for dynamic nuclear
polarization (DNP)-enhanced nuclear magnetic resonance (NMR) applications, composed …

Highly efficient polarizing agents for MAS‐DNP of proton‐dense molecular solids

R Harrabi, T Halbritter, F Aussenac… - Angewandte …, 2022 - Wiley Online Library
Efficiently hyperpolarizing proton‐dense molecular solids through dynamic nuclear
polarization (DNP) solid‐state NMR is still an unmet challenge. Polarizing agents (PAs) …

BDPA-nitroxide biradicals tailored for efficient dynamic nuclear polarization enhanced solid-state NMR at magnetic fields up to 21.1 T

D Wisser, G Karthikeyan, A Lund… - Journal of the …, 2018 - ACS Publications
Dynamic nuclear polarization (DNP) solid-state nuclear magnetic resonance (NMR) has
developed into an invaluable tool for the investigation of a wide range of materials …

Instrumentation for solid-state dynamic nuclear polarization with magic angle spinning NMR

M Rosay, M Blank, F Engelke - Journal of Magnetic Resonance, 2016 - Elsevier
Advances in dynamic nuclear polarization (DNP) instrumentation and methodology have
been key factors in the recent growth of solid-state DNP NMR applications. We review the …

Theoretical aspects of magic angle spinning-dynamic nuclear polarization

F Mentink-Vigier, U Akbey, H Oschkinat, S Vega… - Journal of Magnetic …, 2015 - Elsevier
Abstract Magic Angle Spinning (MAS) combined with Dynamic Nuclear Polarization (DNP)
has been proven in recent years to be a very powerful method for increasing solid-state …