Novel ligand platforms that promote reactivity are of long standing and continued interest in
coordination chemistry, with Schiff base ligands and their metal complexes representing one …

Highlights•Schiff base (HL 2) and its binary Cu (II) and Fe (III) complexes were newly
synthesized and characterized by various spectroscopic methods.•The photoluminescence …

The synthesis and structural characterization of six dicyanamido-cadmium (II) complexes are
reported: catena-[Cd (μ1, 3-dca)(μ1, 5-dca)(3-ampy)](1), catena-[Cd3 (μ1, 3, 5-dca) 2 (μ1, 5 …

Abstract Three cadmium (II) complexes,[Cd (dmpn)(μ-1, 1-N 3) 2] n (1),[Cd (L 1) 2 Cd (N 3)
2](2) and [Cd 2 (L 2) 2 (Cl) 2](3){where dmpn is a bidentate chelating ligand N, N-dimethyl-1 …

In an earlier study we investigated the reaction of iron (II) chloride with NO in a strongly
coordinating ionic liquid 1-ethyl-3-methylimidazolium dicyanamide [emim][dca] and showed …

The two lead (II) coordination polymers [Pb (4, 4′-dm-2, 2′-bpy)(Dca)(NO3)] n (1) and [Pb
(4, 4′-dmo-2, 2′-bpy)(Dca)(NO3)] n (2) were prepared by treatment of lead (II) nitrate …

Reaction of the Schiff base 2, 4-difluoro-6-(((2-(pyrrolidin-1-yl) ethyl) imino) methyl) phenol
(HL) with copper salts and some bridging ligands afforded five complexes,[CuClL](1),[Cu (μ …

Two new dinuclear Cd (II) complexes,[CdL 1 Cl 2] 2· H 2 O (1) and [CdL 1 (N 3) 2] 2· CH 3
OH (2) and one dicyanamide bridged one-dimensional polynuclear network [CdL 1 (μ 1, 5 …

To elucidate the applicability and properties of ionic liquids (ILs) to serve as chemical
reaction media for the activation of small molecules by transition-metal complexes, detailed …

Two neutral pentacoordinate mononuclear cadmium (II) complexes of the type [Cd (L) X
2][L= N-(pyridin-2′-yl) benzylidene)-2-(piperidin-1-yl) ethane-1, 2-diamine; X= Cl,(1) and …