The stabilization and isolation of highly reactive species has long been the subject of
chemical research. This review will focus on a large and important class of reactive species …

In recent decades, it has generally been recognized that carbenes play an important role as
transient intermediates. As a result of a number of stable carbenes having been isolated and …

Disclosed are homoleptic diazabutadiene nickel precursors used for the vapor deposition of
nickel-containing films. The precursors have the general formula Ni (R-DAD) 2, wherein R …

A decade ago we initiated research, the goal of which was isolation of a stable carbene. Our
success has helped to catalyze a resurgence of interest in readily available and easily …

Until recently the low-coordinate compounds of the heavier elements of group 14 were
known only as transient, unstable species which were difficult to isolate. However recent …

The transition-metal (TM) chemistry of heavier tetrylenes (HTs), also known as heavier
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …

Thermodynamic, structural, and magnetic criteria, the properties of the charge distributions,
and low-energy ionization processes are theoretically analyzed to learn about the role of π …

A series of lithium salts of boryl anion, boryllithiums, were synthesized and characterized by
NMR spectroscopy and crystallographic analysis. In addition to the parent boryllithium …

JutZi, P. et al.,“Stabilization of monomeric dichlorogermylene,” Angew, Chem. Int'l, Edit. vol.
12 (1973), No. 12, 1002-1003. JutZi, P. et al.,“Zur reaktivitat der Is-C-bindung in …

Quantum chemical calculations at the MP2 level of theory using relativistic ECPs with large
valence basis sets for the metals are reported for the complexes of CuCl, AgCl, and AuCl …