Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Chalcogen bonding: An overview

L Vogel, P Wonner, SM Huber - … Chemie International Edition, 2019 - Wiley Online Library
In the last few decades,“unusual” noncovalent interactions like anion‐π and halogen
bonding have emerged as interesting alternatives to the ubiquitous hydrogen bonding in …

[HTML][HTML] Chalcogen bonding in coordination chemistry

KT Mahmudov, AV Gurbanov, VA Aliyeva… - Coordination Chemistry …, 2022 - Elsevier
The chalcogen bond (ChB) is defined as a noncovalent interaction between the electron
density deficient region (so-called as σ or π hole) of a covalently bonded chalcogen atom …

The origin of chalcogen-bonding interactions

DJ Pascoe, KB Ling, SL Cockroft - Journal of the American …, 2017 - ACS Publications
Favorable molecular interactions between group 16 elements have been implicated in
catalysis, biological processes, and materials and medicinal chemistry. Such interactions …

Computer modeling of halogen bonds and other σ-hole interactions

MH Kolar, P Hobza - Chemical reviews, 2016 - ACS Publications
In the field of noncovalent interactions a new paradigm has recently become popular. It
stems from the analysis of molecular electrostatic potentials and introduces a label, which …

Sigma-hole interactions in anion recognition

JYC Lim, PD Beer - Chem, 2018 - cell.com
Sigma (σ)-holes are electron-deficient regions that arise from the anisotropic distribution of
electron density on the atom of group 14 (tetrels), 15 (pnictogens), 16 (chalcogens), and 17 …

The bright future of unconventional σ/π‐hole interactions

A Bauzá, TJ Mooibroek, A Frontera - ChemPhysChem, 2015 - Wiley Online Library
Non‐covalent interactions play a crucial role in (supramolecular) chemistry and much of
biology. Supramolecular forces can indeed determine the structure and function of a host …

A million crystal structures: The whole is greater than the sum of its parts

R Taylor, PA Wood - Chemical reviews, 2019 - ACS Publications
The founding in 1965 of what is now called the Cambridge Structural Database (CSD) has
reaped dividends in numerous and diverse areas of chemical research. Each of the million …

Non-covalent interactions in the synthesis of coordination compounds: Recent advances

KT Mahmudov, MN Kopylovich, MFCG da Silva… - Coordination Chemistry …, 2017 - Elsevier
This review describes how non-covalent interactions, such as hydrogen (inter-and
intramolecular, resonance-and charge-assisted hydrogen bonding), halogen, chalcogen …

Pnictogen bonding in coordination chemistry

KT Mahmudov, AV Gurbanov, VA Aliyeva… - Coordination Chemistry …, 2020 - Elsevier
The pnictogen bond (PnB) is a noncovalent attraction between electrophilic pnictogen
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …