Recent advances in polyoxometalate-catalyzed reactions

SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Multifunctional nanocatalysts for tandem reactions: A leap toward sustainability

D Jagadeesan - Applied Catalysis A: General, 2016 - Elsevier
Abstract Design of new multifunctional nanocatalysts is a hot area of research that aims to
introduce multiple types of active sites on a single nanocatalyst. Multifunctional …

Polyoxometalate photocatalysis for liquid-phase selective organic functional group transformations

K Suzuki, N Mizuno, K Yamaguchi - ACS Catalysis, 2018 - ACS Publications
Polyoxometalates (POMs), which are anionic metal oxide clusters, have recently attracted
considerable attention as photocatalysts because of their unique photoinduced charge …

A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone

D Yang, Z Li, Y Lian, Z Fu, T Li, P Ma, G Yang - Chinese Chemical Letters, 2025 - Elsevier
By introduction of hydrogen peroxide into the reaction system of ZrOCl 2· 8H 2 O and K 14
[As 2 W 19 O 67 (H 2 O)], a novel polyoxometalate K 8 Na 19.5 H 0.5 [Zr 2 (O 2) 2 (β-As VW …

Incorporating heterogeneous lacunary Keggin anions as efficient catalysts for solvent-free cyanosilylation of aldehydes and ketones

M Malmir, MM Heravi, Z Yekke-Ghasemi, M Mirzaei - Scientific Reports, 2022 - nature.com
Polyoxometalates (POMs) as efficient catalysts can be used a wide range of chemical
transformations due to their tunable Brønsted/Lewis-acidity and redox properties. Herein, we …

Hexameric to trimeric lanthanide-included selenotungstates and their 2D honeycomb organic–inorganic hybrid films used for detecting ochratoxin A

L Liu, J Jiang, G Liu, X Jia, J Zhao… - ACS Applied Materials …, 2021 - ACS Publications
Two types of organic–inorganic hybrid structure-related lanthanide (Ln)-included
selenotungstates (Ln-SeTs)[H2N (CH3) 2] 11Na7 [Ce4 (H2PTCA) 2 (H2O) 12 (HICA)] 2 …

Reversible switching of single-molecule magnet behaviors by transformation of dinuclear dysprosium cores in polyoxometalates

K Suzuki, R Sato, N Mizuno - Chemical Science, 2013 - pubs.rsc.org
Reversible switching of single-molecule magnet (SMM) behaviors was demonstrated by
structural transformation of dinuclear dysprosium cores in polyoxometalates [{Dy (H2O) 2 …

Visible‐Light‐Induced Photoredox Catalysis with a Tetracerium‐Containing Silicotungstate

K Suzuki, F Tang, Y Kikukawa… - Angewandte Chemie …, 2014 - Wiley Online Library
The development of visible‐light‐induced photocatalysts for chemoselective functional
group transformations has received considerable attention. Polyoxometalates (POMs) are …

Polyoxometalates as a novel class of artificial proteases: Selective hydrolysis of lysozyme under physiological pH and temperature promoted by a cerium (IV) Keggin …

K Stroobants, E Moelants, HGT Ly… - … A European Journal, 2013 - Wiley Online Library
Hen‐egg‐white lysozyme (HEWL) is specifically cleaved at the Trp28–Val29 and Asn44–
Arg45 peptide bonds in the presence of a Keggin‐type [Ce (α‐PW11O39) 2] 10 …

High‐Entropy Metal‐Organic Frameworks (HEMOFs): A New Frontier in Materials Design for CO2 Utilization

RE Sikma, DJ Vogel, RA Reyes… - Advanced …, 2024 - Wiley Online Library
High‐entropy materials (HEMs) emerged as promising candidates for a diverse array of
chemical transformations, including CO2 utilization. However, traditional HEMs catalysts are …