Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands

MA Kinzhalov, EV Grachova… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as
powerful emitters for prospective use in OLEDs and other electroluminescent technologies …

The diverse functions of isocyanides in phosphorescent metal complexes

GD Sutton, ME Olumba, YH Nguyen, TS Teets - Dalton Transactions, 2021 - pubs.rsc.org
In this Perspective, we highlight many examples of photoluminescent metal complexes
supported by isocyanides, with an emphasis on recent developments including several from …

Phosphorescent iridium (III) complexes with acyclic diaminocarbene ligands as chemosensors for mercury

AA Eremina, MA Kinzhalov, EA Katlenok… - Inorganic …, 2020 - ACS Publications
A new application for bis (cyclometalated) iridium (III) species containing ancillary acyclic
diaminocarbene ligands, viz. for sensing of mercury (II) ions, is disclosed. A family of bis …

Synthesis and contemporary applications of platinum group metals complexes with acyclic diaminocarbene ligands

MA Kinzhalov, KV Luzyanin - Russian Journal of Inorganic Chemistry, 2022 - Springer
Complexes of platinum group metals with acyclic diaminocarbene ligands have found
application as transition metal catalysts, photoluminescent materials, chemosensors, and …

Substituent-Dependent Azide Addition to Isocyanides Generates Strongly Luminescent Iridium Complexes

C Jiang, LM Cañada, NB Nguyen… - Journal of the …, 2023 - ACS Publications
Ligand-centered functionalization reactions offer diverse strategies to prepare luminescent
organometallic compounds. These compounds can have unique structures that are not …

Photoluminescence of cyclometalated iridium complexes in poly (methyl methacrylate) films

H Na, PN Lai, LM Cañada, TS Teets - Organometallics, 2018 - ACS Publications
In this work, we describe the emission properties of 12 heteroleptic bis-cyclometalated
iridium complexes immobilized in poly (methyl methacrylate)(PMMA) thin films. The …

Theoretical investigation of electronic structures, second-order NLO responses of cyclometalated Ir (III) and Rh (III) counterpart complexes: effect of metal centers

H Wang, J Ye, Y Qiu, F Chen - New Journal of Chemistry, 2022 - pubs.rsc.org
In this paper, eight complexes M-1, M-2, M-3 and M-4 (M= Ir or Rh) in the general formula [M
(C^ N) 2 (N^ N)](C^ N= cyclometalated ligands and N^ N= ancillary ligands) are …

Panchromatic Excited-State Absorption in Bis-Cyclometalated Iridium Isocyanide Complexes

ME Olumba, RM O'Donnell, TN Rohrabaugh Jr… - Inorganic …, 2022 - ACS Publications
In this work, we introduce a series of cyclometalated iridium complexes and evaluate the
suitability of this class of compounds in nonlinear optical (NLO) applications, with an …

Bis-cyclometalated iridium complexes with chelating dicarbene ancillary ligands

H Na, A Maity, R Morshed, TS Teets - Organometallics, 2017 - ACS Publications
In this work, we report that covalent postsynthetic modification can be used for the
preparation of a class of bis-cyclometalated iridium complexes featuring Chugaev-type …

Cyclometalated iridium–BODIPY ratiometric O 2 sensors

KS Choung, K Marroquin, TS Teets - Chemical Science, 2019 - pubs.rsc.org
Here we introduce a new class of ratiometric O2 sensors for hypoxic environments. Two-
component structures composed of phosphorescent cyclometalated Ir (III) complexes and …