Photochemistry of transition metal hydrides

RN Perutz, B Procacci - Chemical Reviews, 2016 - ACS Publications
Photochemical reactivity associated with metal–hydrogen bonds is widespread among
metal hydride complexes and has played a critical part in opening up C–H bond activation. It …

Heavier tetrylene-and tetrylyne-transition metal chemistry: it's no carbon copy

TJ Hadlington - Chemical Society Reviews, 2024 - pubs.rsc.org
Since the late 19th century, heavier tetrylene-and tetrylyne-transition metal chemistry has
formed an important cornerstone in both main-group and organometallic chemistry alike …

Cooperativity in transition metal tetrylene complexes

RJ Somerville, J Campos - European Journal of Inorganic …, 2021 - Wiley Online Library
Cooperative reactivity between transition metals and ligands, or between two metals, has
created significant opportunities for the development of new transformations that would be …

Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH 3, N 2 H 4, H 2 O, H 2)

M Auer, J Bolten, K Eichele, H Schubert… - Chemical …, 2023 - pubs.rsc.org
Halide abstraction from tetrylidene complexes [TbbE (Br) IrH (PMe3) 3][E= Ge (1), Sn (2)]
and [Ar* E (Cl) IrH (PMe3) 3] gives the salts [TbbEIrH (PMe3) 3][BArF4][E= Ge (3), Sn (4)] …

Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me3P)2(Ph3P)Rh≡E‐Ar*] (E=Sn, Pb)

M Widemann, K Eichele, H Schubert… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Tetrylidynes [(Me3P) 2 (Ph3P) Rh≡ SnAr*](10) and [(Me3P) 2 (Ph3P) Rh≡
PbAr*](11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3P) …

Hydrogen abstraction from organotin di-and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin (II) species and …

CP Sindlinger, L Wesemann - Chemical Science, 2014 - pubs.rsc.org
N-Heterocyclic carbenes are shown to cleanly abstract dihydrogen from organotin di-and
trihydrides to intermediately form the reactive stannylene species [R2Sn] and [R′ SnH] …

Coordination of non-stabilized germylenes, stannylenes, and plumbylenes to transition metals

J Baumgartner, C Marschner - Reviews in Inorganic Chemistry, 2014 - degruyter.com
Complexes of transition metals with heavy analogs of carbenes (tetrylenes) as ligands have
been studied now for some 40 years. The current review attempts to provide an overview …

Versatile Fe–Sn bonding interactions in a metallostannylene system: Multiple bonding and C–H bond activation

RC Handford, MA Nesbit, PW Smith… - Journal of the …, 2021 - ACS Publications
The metallostannylene Cp*(i Pr2MeP)(H) 2Fe-SnDMP (1; Cp*= η5-C5Me5; DMP= 2, 6-
dimesitylphenyl), formed by hydrogen migration in a putative Cp*(i Pr2MeP) HFe [Sn (H) …

Facile Access to Cationic Methylstannylenes and Silylenes Stabilized by E− Pt Bonding and their Methyl Group Transfer Reactivity

R Govindarajan, RR Fayzullin, S Deolka… - … A European Journal, 2024 - Wiley Online Library
We describe a family of cationic methylstannylene and chloro‐and azidosilylene
organoplatinum (II) complexes supported by a neutral, binucleating ligand …

NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand

A Jana, M Majumdar, V Huch, M Zimmer… - Dalton …, 2014 - pubs.rsc.org
Vinylidenes are common in transition metal chemistry with catalytic applications in alkene
and alkyne metathesis. We report here the isolation of a heavier analogue of vinylidene, an …