Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared to the equilibration of the optically populated excited state. This equilibration involves the …
The ultrafast photoinduced ring-opening of 1, 3-cyclohexadiene constitutes a textbook example of electrocyclic reactions in organic chemistry and a model for photobiological …
AI Krylov - The Journal of Chemical Physics, 2020 - pubs.aip.org
Molecular orbital framework is of central importance in chemistry. Often used by chemists and physicists to gain insight into molecular properties, Hartree–Fock or Kohn–Sham …
With the recent advances in ultrabright electron and x-ray sources, it is now possible to extend crystallography to the femtosecond time domain to literally light up atomic motions …
Femtosecond stimulated Raman spectroscopy (FSRS) is an ultrafast nonlinear optical technique that provides vibrational structural information with high temporal (sub‐50 fs) …
AA Ischenko, PM Weber, RJD Miller - Chemical reviews, 2017 - ACS Publications
One of the grand challenges in chemistry has been to directly observe atomic motions during chemical processes. The depiction of the nuclear configurations in space-time to …
Correlated electron systems can undergo ultrafast photoinduced phase transitions involving concerted transformations of electronic and lattice structure. Understanding these …
RJD Miller - Annual review of physical chemistry, 2014 - annualreviews.org
This review documents the development of high–bunch charge electron pulses with sufficient combined spatiotemporal resolution and intensity to literally light up atomic …
The ability to resolve the dynamics of matter on its native temporal and spatial scales constitutes a key challenge and convergent theme across chemistry, biology, and materials …