Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Significant progress has been made in the past 10–15 years on the design, synthesis, and
properties of multimetallic coordination complexes with heterometallic metal–metal bonds …

Many challenging chemical reactions require precious metal catalysts to proceed. Bio-
inspired catalysts featuring multiple earth-abundant metals are an attractive alternative, as …

Conspectus Alfred Werner, who pioneered the field of coordination chemistry, envisioned
coordination complexes as a single, transition metal atom at the epicenter of a vast ligand …

Ligands are known to play a crucial role in the construction of complexes with metal–metal
bonds. Compared with metal–metal bonds involving d-block transition metals, knowledge of …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Due to their fascinating structures and heterometallic synergistic effects in catalysis,
heterometallic clusters with metal–metal (M–M) bonds have attracted the interest of chemists …

Heterobimetallic complexes are studied for their ability to mimic biological systems as well
as active sites in heterogeneous catalysts. While specific interest in early/late …

To understand the metal–metal bonding and conformational flexibility of first-row transition
metal heterobimetallic complexes, a series of heterobimetallic Ti/M and V/M complexes (M …

Heterometallic multiple bonds between niobium and other transition metals have not been
reported to date, likely owing to the highly reactive nature of low-valent niobium centers …