This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Over the past few decades, there have been major developments in transition metal-
catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide …

Carbonyl derivatives widely exist in pharmaceuticals, agricultural chemicals, materials, and
natural products. Developing novel, efficient, and green carbonylation methods represent …

A palladium-catalyzed asymmetric Markovnikov hydroaminocarbonylation of alkenes with
anilines has been developed for the atom-economical synthesis of 2-substituted …

Can green chemistry be the right reading key to let organocatalyst design take a step
forward towards sustainable catalysis? What if the intriguing chemistry promoted by more …

Conspectus Oxidation reactions play a central role in organic synthesis, and it is highly
desirable that these reactions are mild and occur under catalytic conditions. In Nature …

Carbon monoxide, which is an abundant and inexpensive carbonyl source, has been widely
applied to synthesize carbonyl-containing compounds, for example ketones, esters, and …

Reported herein is the development of the first enantioselective monodentate ligand
assisted Pd‐catalyzed domino Heck carbonylation reaction with CO. The highly …

In this account, we review our efforts in the field of carbonylation reactions promoted by
palladium iodide-based catalysts, which have proven to be particularly efficient in diverse …

Herein, we report an electrochemical oxidative palladium‐catalyzed carbonylation‐
carbocyclization of enallenols to afford γ‐lactones and spirolactones, which proceeds with …