Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

The synthesis and structural characterization of a series of supramolecular complexes of
bicyclic cationic pyridine-fused 1, 2, 4-selenodiazoles with various anions is reported. The …

We report the preparation of a new organic σ‐donor with a C6H4‐linker between an N‐
heterocyclic carbene (NHC) and an exocyclic methylidene group, which we term N …

The series of benzylic-substituted 1, 2, 4-selenodiazolium salts were prepared via
cyclization reaction between 2-pyridylselenyl chlorides and nitriles and fully characterized …

Preparation of novel triarylazoimidazole trichlorogold (III) complexes is described. The new
compounds were characterized using C, H, N elemental analyses, IR, UV/Vis and X-ray …

Chalcogenodiazoles have been intensively studied in recent years in the context of their
supramolecular chemistry. In contrast, the newly discovered cationic 1, 2, 4-selenodiazole …

An unprecedented NHC-catalyzed generation of p-quinodimethanes via ε-umpolung of 4-
(chloromethyl) benzaldehydes and the following ε-addition to active ketones was developed …

The synthesis of 2-pyridyltellurenyl bromide via Br2 oxidative cleavage of the Te–Te bond of
dipyridylditelluride is reported. Single-crystal X-ray diffraction analysis of 2-pyridyltellurenyl …

1-Aryl-3-(4-bromophenyl)-4, 4-dichloro-1, 2-diazabuta-1, 3-dienes were synthesized via
copper-catalyzed reaction of 4-bromobenzaldehyde arylhydrazones with CCl 4. X-ray …

Diradicals have been of tremendous interest for over a century ever since the first reports of
p‐and m‐phenylene‐bridged diphenylmethylradicals in 1904 by Thiele and 1915 by …