Advances in Pd-catalyzed C–C bond formation in carbohydrates and their applications in the synthesis of natural products and medicinally relevant molecules

N Hussain, A Hussain - Rsc Advances, 2021 - pubs.rsc.org
Advances in the Pd-catalyzed synthesis of C-glycosides and branched sugars are
summarized herein and the strategies are categorized based on named reactions or types of …

Furan platform chemicals beyond fuels and plastics

R Bielski, G Grynkiewicz - Green Chemistry, 2021 - pubs.rsc.org
Herein, we offer some perspective on the metamorphosis that has already begun to take
place in substantial parts of the chemical industry, ie, a switch from traditional resources …

2‐Halo Glycals as “Synthon” for 2‐C‐Branched Sugar: Recent Advances and Applications in Organic Synthesis

N Hussain, A Ahmed… - Asian Journal of Organic …, 2020 - Wiley Online Library
Glycals are unsaturated sugars having an enolic double bond present inside the ring and
act as a versatile synthon for the synthesis of natural products and biologically important …

Copper(II)‐Mediated Intermolecular Radical [3+2]‐Annulation of N,N‐Dimethyl Enaminones: Direct Access to 5‐Acyl‐3‐Furancarboxaldehydes

B Zhang, P Zhou, H Xu, J Huang, Y Sun… - … Synthesis & Catalysis, 2021 - Wiley Online Library
Copper (II)‐mediated unprecedented intermolecular radical [3+ 2] annulation of N, N‐
dimethyl enaminones has been developed. The protocol is promoted simply by copper (II) …

N-Halo reagents: Modern synthetic approaches for heterocyclic synthesis

VSC de Andrade, MCS de Mattos - Synthesis, 2019 - thieme-connect.com
Heterocyclic chemistry is an essential frontier in science and a source of novel biologically
active compounds. The development of innovative synthetic methodologies that allows …

Versatile applications of 3-OxoGlycals: A review

S Dubbu - Carbohydrate Research, 2024 - Elsevier
Oxoglycals are versatile building blocks with extensive applications in glycochemistry,
organic, and bio-organic sciences. They serve as powerful synthons, enabling the …

Versatile synthesis of 2-functionalized dihydrothiazolo[2,3-b]quinazolines through regioselective electrophilic intramolecular heterocyclization of 3-alkenyl-2 …

DZ Kut, MM Kut, EM Ostapchuk… - … , Sulfur, and Silicon …, 2024 - Taylor & Francis
Electrophilic intramolecular heterocyclizations of 3-alkenyl-2-thioxoquinazolin-4-ones,
induced by halogens, NBS, sulfuryl chloride, protic acids, selenium, or tellurium halides …

NFSI mediated C3-ether oxidation of glycals for the synthesis of hex-3-enuloses

P Das, R Thakur - Carbohydrate Research, 2024 - Elsevier
Hex-3-enuloses constitute a vital carbohydrate synthetic intermediate that provide access to
wide range of chiral molecules through diverse derivatizations. Herein we report synthesis of …

Unleashing the Power of Domino Reactions on Carbohydrates: State of the Art

G Antonini, L Petrosilli, I Giussani… - European Journal of …, 2024 - Wiley Online Library
The intricate nature of carbohydrate structures has prompted the scientific community to
seek efficient protocols for their manipulation. Lengthy synthetic pathways, often necessary …

Base Induced Chiral Substituted Furans and Imidazoles from Carbohydrate-Derived 2-Haloenones

K Mal, I Das - The Journal of Organic Chemistry, 2016 - ACS Publications
Chiral substituted furans and imidazoles are key intermediates to access biologically
important molecules. We describe herein a catalyst/ligand free cascade Michael-type …