Chirality is an omnipresent structural feature found in nature. The transfer and amplification
of chirality are widely recognized phenomena. In appropriate solvents, chiral molecules can …

Chirality is a central feature in the evolution of biological systems, but the reason for
biology's strong preference for specific chiralities of amino acids, sugars, and other …

The control of tetrahedral carbon stereocentres remains a focus of modern synthetic
chemistry and is enabled by their configurational stability. By contrast, trisubstituted nitrogen …

A series of doubly fused triarylamines containing conformationally stable stereogenic
nitrogen centers has been constructed through palladium-catalyzed enantioselective C–H …

Atropisomeric biaryls have found crucial applications in versatile chiral catalysts as well as
in ligands for transition metals. Herein, we have developed an efficient crystallization …

A sulfur stereogenic center is found in naturally occurring compounds and constitutes an
important design element for pharmaceuticals and chiral auxiliaries. In view of the broad …

The isolation and catalytic enantioselective synthesis of configurationally stable S‐
stereogenic sulfonium ylides have been significant challenges in the field of asymmetric …

Nitrogen stereocenters are common chiral units in natural products, pharmaceuticals, and
chiral catalysts. However, their research has lagged largely behind, compared with carbon …

Electrosynthesis is a method of choice for designing new synthetic routes owing to its ability
to selectively conduct reactions at controlled potentials, high functional group tolerance, mild …

Constructing nitrogen-doped porous carbons with high specific surface area, rapid mass
transfer channels, and positive charge is a crucial requirement for high-performance …