Tri-and tetrasubstituted olefins are widely present in biologically active molecules and
functional materials. However, the methods for the stereoselective construction of such …

Propargyl alcohols are widely used in organic reactions. Their great success is rooted in the
presence of multiple functional groups. This review will focus on six types of mechanisms:(i) …

Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …

The introduction of fluorine‐containing groups into organic molecules can significantly affect
their physical and chemical properties and has long been used as an effective strategy for …

A base-assisted metal species modulation mechanism enables Ni-catalyzed
stereodivergent transfer semihydrogenation of alkynes with water, delivering both olefinic …

A remote catalytic reductive sp2 C–H carboxylation of arenes with CO2 (1 bar) via 1, 4-Ni
migration is disclosed. This protocol constitutes the first catalytic 1, 4-Ni migration reported to …

Transition-metal-catalytic domino reactions represent important advances in synthetic
organic chemistry. Their development benefits synthesis by providing highly efficient and …

The development of synthetic methods to produce highly functionalized chiral 3‐pyrrolines is
of indisputable importance because of their prevalence in natural and synthetic bioactive …

Transition metal-catalyzed asymmetric cyclization of 1, 6-enynes is a powerful tool for the
construction of chiral nitrogen-containing heterocycles. Despite notable achievements, these …

The use of arylboron reagents in metal‐catalyzed domino addition–cyclization reactions is a
well‐established strategy for the preparation of diverse, highly functionalized carbo‐and …