Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

In the last few years, considerable progress has been made in the synthesis and
characterization of complexes containing actinide–ligand multiple bonds, especially in …

Understanding and exploiting the redox properties of uranium is of great importance
because uranium has a wide range of possible oxidation states and holds great potential for …

Terminal uranium oxido, sulfido, and selenido metallocenes were synthesized, and their
reactivity was comprehensively studied. Heating of an equimolar mixture of [η5-1, 2, 4 …

The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

Single atoms of uranium supported on molybdenum sulfide surfaces (U@ MoS2) have been
recently demonstrated to facilitate the hydrogen evolution reaction (HER) through …

We report attempts to prepare uranyl (VI)-and uranium (VI) carbenes utilizing deprotonation
and oxidation strategies. Treatment of the uranyl (VI)-methanide complex [(BIPMH) UO2Cl …

This Perspective provides a detailed overview of the chemistry of low-valent (di-and
trivalent) uranium. The reactivity of uranium (II) and uranium (III) complexes is discussed …

The synthesis, structure, and reactivity of thorium oxo and sulfido metallocenes have been
comprehensively studied. Heating of an equimolar mixture of the dimethyl metallocene [η5 …

Reduction of [{η5-1, 2, 4-(Me3Si) 3C5H2} 2UCl2](1) using potassium graphite (KC8) in the
presence of 2, 2′-bipyridine forms the uranium bipyridyl metallocene [{η5-1, 2, 4-(Me3Si) …