One hundred years of helicene chemistry. Part 1: non-stereoselective syntheses of carbohelicenes

M Gingras - Chemical Society Reviews, 2013 - pubs.rsc.org
Carbohelicenes belong to a class of fascinating, chiral, and helicoidal molecules, which
have a rich history in chemistry since the very beginning of the 20th century. A renewed …

Catalytic carbophilic activation: catalysis by platinum and gold π acids

A Fürstner, PW Davies - Angewandte Chemie International …, 2007 - Wiley Online Library
The ability of platinum and gold catalysts to effect powerful atom‐economic transformations
has led to a marked increase in their utilization. The quite remarkable correlation of their …

Relativistic effects in homogeneous gold catalysis

DJ Gorin, FD Toste - Nature, 2007 - nature.com
Transition-metal catalysts containing gold present new opportunities for chemical synthesis,
and it is therefore not surprising that these complexes are beginning to capture the attention …

Gold and platinum catalysis—a convenient tool for generating molecular complexity

A Fürstner - Chemical Society Reviews, 2009 - pubs.rsc.org
This critical review intends to familiarize the reader with the essence of π-acid catalysis, in
particular with reactions or reaction cascades effected by gold and platinum complexes …

Cycloisomerization of 1,n‐Enynes: Challenging Metal‐Catalyzed Rearrangements and Mechanistic Insights

V Michelet, PY Toullec, JP Genêt - … Chemie International Edition, 2008 - Wiley Online Library
Metal‐catalyzed cycloisomerization reactions of 1, n‐enynes have appeared as
conceptually and chemically highly attractive processes as they contribute to the highly …

Synthesis of phenanthrenes and polycyclic heteroarenes by transition‐metal catalyzed cycloisomerization reactions

V Mamane, P Hannen, A Fürstner - Chemistry–A European …, 2004 - Wiley Online Library
Readily available biphenyl derivatives containing an alkyne unit at one of their ortho‐
positions are converted into substituted phenanthrenes on exposure to catalytic amounts of …

Katalytische carbophile Aktivierung: Platin‐und Gold‐π‐Säuren als Katalysatoren

A Fürstner, PW Davies - Angewandte Chemie, 2007 - Wiley Online Library
Platin‐und Goldkatalysatoren gewinnen aufgrund ihrer hohen Effizienz und erstaunlichen
Vielfalt für atomökonomische Umsetzungen rasch an Bedeutung. Dabei erlaubt es die …

Platinum-and gold-catalyzed cycloisomerization reactions of hydroxylated enynes

V Mamane, T Gress, H Krause… - Journal of the American …, 2004 - ACS Publications
Exposure of enynes containing a hydroxyl group at one of the propargylic positions to
catalytic amounts of either PtCl2 or (PPh3) AuCl/AgSbF6 results in a selective …

Heterocycles by PtCl2-Catalyzed Intramolecular Carboalkoxylation or Carboamination of Alkynes

A Fürstner, PW Davies - Journal of the American Chemical …, 2005 - ACS Publications
PtCl2 constitutes a convenient catalyst for intramolecular hydroalkoxylation,
carboalkoxylation, hydroamination, and carboamination reactions of alkynes, effecting the …

Ring closing enyne metathesis: A powerful tool for the synthesis of heterocycles

H Villar, M Frings, C Bolm - Chemical Society Reviews, 2007 - pubs.rsc.org
The ring closing metathesis (RCM) is a powerful method in organic synthesis for the
preparation of cyclic compounds by formation of new carbon–carbon bonds. In the past …