Bio-based polymers with performance-advantaged properties

RM Cywar, NA Rorrer, CB Hoyt, GT Beckham… - Nature Reviews …, 2022 - nature.com
Bio-based compounds with unique chemical functionality can be obtained through selective
transformations of plant and other non-fossil, biogenic feedstocks for the development of …

Translational applications of hydrogels

S Correa, AK Grosskopf, H Lopez Hernandez… - Chemical …, 2021 - ACS Publications
Advances in hydrogel technology have unlocked unique and valuable capabilities that are
being applied to a diverse set of translational applications. Hydrogels perform functions …

Disulfide-mediated reversible polymerization toward intrinsically dynamic smart materials

Q Zhang, DH Qu, BL Feringa… - Journal of the American …, 2022 - ACS Publications
The development of a dynamic chemistry toolbox to endow materials dynamic behavior has
been key to the rational design of future smart materials. The rise of supramolecular and …

Dynamic and reconfigurable materials from reversible network interactions

MJ Webber, MW Tibbitt - Nature Reviews Materials, 2022 - nature.com
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …

Dynamic covalent polymer networks: a molecular platform for designing functions beyond chemical recycling and self-healing

N Zheng, Y Xu, Q Zhao, T Xie - Chemical Reviews, 2021 - ACS Publications
Dynamic covalent polymer networks (DCPN) have historically attracted attention for their
unique roles in chemical recycling and self-healing, which are both relevant for sustainable …

Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Defining the macromolecules of tomorrow through synergistic sustainable polymer research

FM Haque, JSA Ishibashi, CAL Lidston, H Shao… - Chemical …, 2022 - ACS Publications
Transforming how plastics are made, unmade, and remade through innovative research and
diverse partnerships that together foster environmental stewardship is critically important to …

Elastic vitrimers: Beyond thermoplastic and thermoset elastomers

J Luo, Z Demchuk, X Zhao, T Saito, M Tian, AP Sokolov… - Matter, 2022 - cell.com
Thermoset elastomers are widely used in industry and frontier research due to their
advantage of mechanical robustness, high thermal/chemical resistance, and good …

Trends in the Diels–Alder reaction in polymer chemistry

B Briou, B Améduri, B Boutevin - Chemical Society Reviews, 2021 - pubs.rsc.org
The Diels–Alder (DA) reaction is regarded as quite a useful strategy in organic and
macromolecular syntheses. The reversibility of this reaction and the advent of self-repair …

Structure–reactivity–property relationships in covalent adaptable networks

V Zhang, B Kang, JV Accardo… - Journal of the American …, 2022 - ACS Publications
Polymer networks built out of dynamic covalent bonds offer the potential to translate the
control and tunability of chemical reactions to macroscopic physical properties. Under …